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Title:
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Reaction of a bulky phosphite with [Ru3(CO)12]: the molecular structure of one of the decomposition products |
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Author:
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Magwaza, A.O.; Meijboom, R.; Muller, A.; Mavunkal, I.J. |
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Abstract:
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Mono- and bis-substituted phosphite complexes [Ru3(CO)12 x Lx] (L = tris(2,4-di-tert-butylphenyl) phosphite; x = 1, 2) were synthesized
by simple substitution reactions, and were characterized by spectroscopic methods. The monosubstituted ruthenium complex disproportionates
in acetone producing a mononuclear ruthenium complex as one of the decomposition products. Single crystal X-ray
diffraction analysis established the molecular structure of this new compound. |
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URI:
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http://hdl.handle.net/10311/259
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Date:
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2008 |
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Publisher:
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Elsevier B.V. www.elsevier.com/locate/ica |
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xmlui.dri2xhtml.METS-1.0.item-type:
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Article |