Browsing by Author "Kapchec, G.W.F."
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Ngadjui, B.T.; Abegaz, B.M.; Keumedjio, F.; Folefoc, G.N.; Kapchec, G.W.F. (Elsevier Science Ltd. www.elsevier.com/locate/phytochem, NaN, 2002)[more][less]
Abstract: Three clerodane diterpenoids, crotozambefurans A, B and C were isolated from the stem bark of Croton zambesicus together with the known clerodane crotocorylifuran and two trachylobanes: 7b-acetoxytrachyloban-18-oic acid and trachyloban-7b, 18-diol. Betulinol, lupeol, sitosterol and its 3b-glucopyranosyl derivative were also obtained. The structures of crotozambefurans A, B and C were determined, respectively, as: 15,16-epoxy-1,3,13(16),14-clerodatetraen-20,12-olide-18,19-dioic acid dimethylester, 15,16-epoxy- 1,3,13(16),14-clerodatetraen-18,19,20-trioic acid trimethylester and 15,16-epoxy-3,13(16),14-clerodatrien-19,1a:20,12-diolide-18-oic acid methylester, using spectroscopic analysis, especially, NMR spectra in conjunction with 2D experiments, COSY, HSQC, HMBC and TOCSY. URI: http://hdl.handle.net/10311/251 Files in this item: 2
Diterpenoids from the stem bark.pdf (2.493Mb)license.txt (1.998Kb)
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