Browsing Research articles (Dept of Geology) by Author "Huntsman-Mapila, P."
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Huntsman-Mapila, P.; Kampunzu, A.B.; Ringrose, S.; Vink, B. (Elsevier www.elsevier.com/locate/sedgeo, NaN, 2005)[more][less]
Abstract: The siliciclastic sediments of the Okavango inland Delta of northwest Botswana have a modal composition of quartz arenites and result from a complex history, including transport by river and deposition in a nascent rift basin located in a desert environment with input of aeolian sands. The geochemical composition of sediments from the Okavango Delta was determined in order to constrain the role of weathering at the source and the composition of the source rocks. The chemical analyses and the interelement ratios show a broad compositional range usually encompassing the PAAS composition. The chemical index of alteration (CIA) values and the A–CN–K diagram define an evolution trend which can be interpreted using a mixing model involving a strongly weathered component which corresponds to the sedimentary fraction transported by the Okavango River and a relatively immature component which corresponds to the aeolian sand component of the Okavango sediments. Field geological data supported by geochemical ratios involving elements with affinity for mafic–ultramafic and felsic rocks such as Th/Cr, Th/Sc, La/Sc, La/Co and Eu/Eu* support a source area including mafic–ultramafic and felsic rocks, with or without intermediate rocks. The relationships between certain elements (Cr–Ni, Na2O–Al2O3, K2O–Al2O3) refine the interpretation by pointing to the existence of at least three source rock end-members, including a felsic rock source and pyroxene-rich and olivine-rich mafic–ultramafic source rocks. Proterozoic granitoid–gabbro and related volcanic and ortho-metamorphic rock complexes exposed in NW Botswana and adjacent Angola and Namibia are the source rocks of the sediment component which was mixed with aeolian sand and interacted with a variable proportion of diagenetic carbonates to produce the Okavango sediments. URI: http://hdl.handle.net/10311/382 Files in this item: 1
Kampunzu2005OkavangoDeltasediments.pdf (1.941Mb) -
Ringrose, S.; Harris, C.; Huntsman-Mapila, P.; Vink, B.W.; Diskins, S.; Vanderpost, C.; Matheson, W. (Elsevier www.elsevier.com/locate/sedgeo, NaN, 2009)[more][less]
Abstract: Trace elements togetherwith some O and C isotope analysiswere undertaken on duricrust strandline deposits in the palaeo-Makgadikgadi sub-basin (PMSB) to provide insight into palaeo-climatic conditions through the interpretation of calcrete, silcrete–calcrete intergrade and silcrete deposits. Trace element content and relative abundance suggest that the duricrust origins are associated with the long-term weathering of the Karoo Large Igneous Province which underlies the PMSB. This work shows that duricrust origins are related to Ca2+ and Si (and associated trace elements) being transported mainly through the groundwater and then subsequently precipitated at different strandline elevations over time. Local groundwater feeding in towards the pan margin and accumulating in near-neutral pan-marginal pools, appears to facilitate Si concentration and permeation of pre-existing calcretes. The silica precipitates as the pH drops when renewed freshwater enters the pools. Hence the inferred palaeo-climatic regime for silcretisationmay be similar to that occurring in Botswana at present being dry semi-arid with lowseasonal rainfall. In contrast the extensive calcrete precipitation in the strandlines results from abundant Ca2+ in adjacent waters which appear to be derived from both local and regional sources. The arrival of Ca2+ from regional sources (shown by trace element evidence) infers heavy rainfall in the upper catchment suggesting a major humid event followed by regional drying. Palaeo-climatic inferences suggest the juxtaposition ofmajor humid events interspersedwithmore normal semi-arid palaeo-climateswith an exception obtained from isotope data, of drier and cooler conditions than usual for the region around 80–90000 years ago. Whereas trace element data can greatly assist in the interpretation of complex deposits such as duricrusts, care should be taken over the use of particular ratios (such as Yb/Gd ratio) which may produce spurious results. URI: http://hdl.handle.net/10311/560 Files in this item: 1
RINGROSE2009Makgadikgadi Pans.pdf (3.500Mb) -
Ringrose, S.; Huntsman-Mapila, P.; Kampunzu, A.B.; Downey, W.; Coetzee, S.; Vink, B.W.; Matheson, W.; Vanderpost, C. (Elsevier www.elsevier.com/locate/palaeo, NaN, 2005)[more][less]
Abstract: This work considers new evidence for palaeo environmental change taking place during the Pleistocene in northern Botswana. Duricrusted strandlines along the northeastern margin of Sua Pan provide palaeo-environmental data pertaining to the Makgadikgadi subbasin (MSB) with inferences regarding the larger Makgadikgadi–Okavango–Zambezi (MOZ) rift depression. Field, XRD and geochemical data show that MSB strandlines comprise calcretes (LU1 type), MgO-rich calcretes with silica (LU2 type), sil-calcrete (LU3 type) and silcrete (LU4 type). Early freshwater episodes appear to have been followed by calcrete-dominated drying phases interspersed with repeated silcretisation. Calcretisation through pan littoral sediments may have been both biogenically and environmentally induced. Calcite precipitation was in part controlled by the Mg/Ca ratio of pore water in the pan littoral zone suggesting closed basin type evaporative conditions, which were followed by a major desiccation interval. Phases of silcrete precipitation appear to be related to periods when the geochemistry of the lake littoral more closely resembled present-day Na–CO3–SO4–Cl-type brines. Silica saturated acidic, moderately saline groundwater preceded Si precipitation which took place as the pH reduced. Si mobilisation occurred (inter alia) as a result of quartz grain dissolution enhanced by diatoms, bacteria and algal growth in the moist pan littoral. SiO2-rich pore waters migrated through cracked and desiccated calcrete into areas of lower salinity and lower pH resulting in preferential calcite removal and silcrete precipitation. Approximate TL dates imply that exposed littoral sand underwent calcretisation during the drying phases of extensive palaeo-lakes which occurred prior to 110 ka, 80–90 ka and 41–43 ka. These wet periods compare fairly well with Vostok core chronologies for southern Africa. URI: http://hdl.handle.net/10311/794 Files in this item: 1
Kampunzu2006Sedimentological.pdf (3.498Mb) -
Huntsman-Mapila, P.; Ringrose, S.; Mackay, A.W.; Downey, W.S.; Modisi, M.; Coetzee, S.H.; Tiercelin, J.-J.; Kampunzu, A.B.; Vanderpost, C. (Elsevier, www.sciencedirect.com, NaN, 2006)[more][less]
Abstract: Sediment samples from a continuous 4.6m profile in the dry bed of Lake Ngami in NW Botswana were analysed for geochemistry and dated using both 14C and TL methods. Certain units in the profile were found to be diatom rich and these, with the geochemical results, were used as indicators of high and low lake levels within the basin. The Lake Ngami sediments contain a high proportion of SiO2 (51–92.5 wt%, avg. 72.4 wt%) and variable levels of Al2O3 (2.04–17.2 wt%, avg. 8.88 wt%). Based on elevated Al2O3 and organic matter (LOIorgC) results, lacustrine conditions occurred at ca. 42 ka until 40 ka and diatom results suggest that relatively deep but brackish conditions prevailed. At 40 ka, the lacustrine sedimentary record was terminated abruptly, possibly by tectonic activity. At ca. 19 ka, shallow, aerobic, turbulent conditions were prevalent, but lake levels were at this time increasing to deeper water conditions up until ca. 17 ka. This period coincides with the Late Glacial Maximum, a period of increased aridity in the central southern Africa region. Generally, increasing Sr/Ca ratios and decreasing LOIorgC and Al2O3, from ca. 16 to 5 ka, suggest decreasing inflow into the basin and declining lake levels. Based on the enrichment of LREE results, slightly alkaline conditions prevailed at ca. 12 ka. Diatom results also support shallow alkaline conditions around this time. These lake conditions were maintained primarily by local rainfall input as the region experienced a warmer, wetter phase between 16 and 11 ka. Lake levels rose rapidly by 4 ka, probably in response to enhanced rainfall in the Angolan catchment. These results indicate that lake levels in the Lake Ngami basin are responding to rainfall changes in the Angolan catchment area and local rainfall. The results confirm that the present-day anti-phase rainfall relationship between southern Africa and regions of equatorial Africa was extant during the late Quaternary over the Angolan highlands and NW Botswana. URI: http://hdl.handle.net/10311/891 Files in this item: 1
Modisi2006SedimentaryRecord.pdf (1.674Mb)
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