Browsing Research articles (Dept of Geology) by Issue Date
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Mapeo, R.B.M.; Kampunzu, A.B.; Armstrong, R.A. (Geological Society of South Africa. http://sajg.geoscienceworld.org/, June NaN, 2000)[more][less]
Abstract: The Precambrian rocks of northern Botswana comprise poorly exposed igneous complexes, high-grade metamorphic rocks, as well as sedimentary sequences including mainly siliciclastic and carbonate rocks. New U-Pb SHRIMP data are presented for detrital zircons from siliciclastic rocks collected from the Shakawe area in northern Botswana. These data show three main age groups at c. 1020 Ma, 1090 Ma, and 2050 Ma which support contentions for local provenance of the sediments. They also fix the maximum age of the deposition of these siliciclastic rocks at 1020 Ma. The results support field evidence suggesting that the siliciclastic rocks exposed in the Shakawe zone are part of the Ghanzi-Chobe Supergroup. URI: http://hdl.handle.net/10311/371 Files in this item: 1
mapeodoc.pdf (1.611Mb) -
Ringrose, S.; Kampunzu, A.B.; Vink, B.W.; Matheson, W.; Downey, W.S. (John Wiley & Sons, Ltd. http://www3.interscience.wiley.com/journal/117935722/grouphome/home.html, NaN, 2002)[more][less]
Abstract: Quaternary sedimentation in the Moshaweng dry valley of southeastern Botswana is evaluated on the basis of geomorphological evolution and sedimentological analyses. Stratigraphic evidence reveals an 'upper surface (1095 m) containing abundant sil-calcrete, an intermediate surface (1085 m) in which sil-calcrete underlies nodular calcrete and lower (1075 m) surface in which sil-calcrete and nodular calcrete are interbedded. This subdivision is reflected in the geochemical composition of the sediments which show an overall trend of decreasing Si02 content (and increasing CaC03 content) with depth from the highest to the lowest surface levels. The calcretes and sil-calcretes represent modifications of pre-existing detrital Kalahari Group sand and basal Kalahari pebbles which thinned over a Karoo bedrock high. Modification took place during wet periods when abundant Ca++ -rich groundwater flowed along the structurally aligned valley system. With the onset of drier conditions, water table fluctuations led to the precipitation of nodular calcretes in the phreatic layer to a depth of about 20 m. A major geochemical change resulted in the preferential silicification of the nodular calcrete deposits. Conditions for silica mobilization may be related to drying-induced salinity and in situ geochemical differentiation brought about by pebble dissociation towards the top of the sediment pile. As calcretization and valley formation progressed to lower levels, silica release took place on a diminishing scale. Thermoluminescence dating infers a mid-Pleistocene age for sil-calcrete formation suggesting that valley evolution and original calcrete precipitation are much older. Late st~ge dissolution of CaC03 from pre-existing surface calcretes or sil-calcretes led to the formation of pedogenic case-hardened deposits during a time of reduced flow through the Moshaweng system possibly during the upper or late Pleistocene. URI: http://hdl.handle.net/10311/310 Files in this item: 1
Ringrose_ESPL_2002.pdf (3.095Mb) -
Ranganai, R.T.; Kampunzu, A.B.; Atekwana, E.A.; Paya, B.K.; King, J.G.; Koosimile, D.I.; Stettler, E.H. (Royal Astronomical Society. http://www.wiley.com/bw/journal.asp?ref=0956-540X&site=1, NaN, 2002)[more][less]
Abstract: The Limpopo Belt of southern Africa is a Neoarchean orogenic belt located between two older Archean provinces, the Zimbabwe craton to the north and the Kaapvaal craton to the south. Previous studies considered the Limpopo Belt to be a linearly trending east-northeast belt with a width of ~250 km and ~600 km long. We provide evidence from gravity data constrained by seismic and geochronologic data suggesting that the Limpopo Belt is much larger than previously assumed and includes the Shashe Belt in Botswana, thus defining a southward convex orogenic arc sandwiched between the two cratons. The 2 Ga Magondi orogenic belt truncates the Limpopo–Shahse Belt to the west. The northern marginal, central and southern marginal tectonic zones define a single gravity anomaly on upward continued maps, indicating that they had the same exhumation history. This interpretation requires a tectonic model involving convergence between the Kaapvaal and Zimbabwe cratons during a Neoarchean orogeny that preserved the thick cratonic keel that has been imaged in tomographic models. URI: http://hdl.handle.net/10311/326 Files in this item: 1
Ranganai_GJI_2002.pdf (1.361Mb) -
Alemaw, B.F.; Chaoka, T.R. (Pergamon www.elsevier.com/locate/pce, NaN, 2003)[more][less]
Abstract: A distributed GIS-based hydrological model is developed using GIS and computational hydrology techniques. The model is based on water balance consideration of the surface and subsurface processes. The surface water balance processes include precipitation infiltration, overland runoff, evapo-transpiration and canopy surface interception losses on daily time steps; The subsurface process considers soil moisture accounting on a monthly basis. The model was used to estimate generated runoff from matrix of specific geo-referenced grids representing Southern Africa. All regional and seasonal dispensation of water balances have been based on standard GIS formats for storage, spatial display and interpretation of results. Considering the 1961–1990 climatic period, we have mapped the regional variation of the mean annual soil moisture (SM), actual evapo-transpiration (AET), and generated runoff (ROF) across Southern Africa or known as the SADC region. The model estimates the mean SM of the region to be about 148 mm/year. There is a wide spatial range in the distribution of SM over the region due to the fact that the absolute soil moisture is dependent on the water retention properties of the soils considered across the region. The model prediction of the mean annual AET in the region reaches a maximum of 1500 mm, with mean 420 mm. The mean annual generated runoff from the land catchment in the region is about 151 mm/year although there is a significant inter-regional variation among the SADC countries, which is a function of the variation in the vegetation cover, soil and climate variation. Lower runoff regimes are dominant in arid areas in Botswana, Namibia and south-western part of the Republic of South Africa. Higher runoff regimes are the Northern and Western Tanzania, along the east coastal portions of Mozambique, central Mozambique, western Zambia and Malawi. URI: http://hdl.handle.net/10311/494 Files in this item: 1
ALEMAW2003CONTINENTAL SCALE.pdf (623.4Kb) -
Kampunzu, A.B.; Tombale, A.R.; Zhaia, M.; Bagai, Z.; Majaule, T.; Modisi, M.P. (Elsevier www.elsevier.com/locate/lithos, NaN, 2003)[more][less]
Abstract: The Neoarchaean Tati granite–greenstone terrane occurs within the southwestern part of the Zimbabwe craton in NE Botswana. It comprises 10 intrusive bodies forming part of three distinct plutonic suites: (1) an earlier TTG suite dominated by tonalites, trondhjemites, Na-granites distributed into high-Al (Group 1) and low-Al (Group 2) TTG sub-suite rocks; (2) a Sanukitoid suite including gabbros and Mg-diorites; and (3) a younger high-K granite suite displaying I-type, calc-alkaline affinities. The Group 1 TTG sub-suite rocks are marked by high Sr/Y values and strongly fractionated chondrite-normalized rare earth element (REE) patterns, with no Eu anomaly. The Group 2 TTG sub-suite displays higher LREE contents, negative Eu anomaly and small to no fractionation of HREE. The primordial mantle-normalized patterns of the Francistown TTGs are marked by negative Nb–Ti anomalies. The geochemical characteristics of the TTG rocks are consistent with features of silicate melts from partial melting of flat subducting slabs for the Group 1 sub-suite and partial melting of arc mafic magmas underplated in the lower crust for the Group 2 sub-suite. The gabbros and high-Mg diorites of the Sanukitoid suite are marked by Mg#>0.5, high Al2O3 (>>16%), low TiO2 ( < 0.6%) and variable enrichment of HFSE and LILE. Their chondrite-normalized REE patterns are flat in gabbros and mildly to substantially fractionated in high-Mg diorites, with minor negative or positive Eu anomalies. The primordial mantle-normalized diagrams display negative Nb–Ti (and Zr in gabbros) anomalies. Variable but high Sr/Y, Sr/Ce, La/Nb, Th/Ta and Cs/La and low Ce/Pb ratios mark the Sanukitoid suite rocks. These geochemical features are consistent with melting of a sub-arc heterogeneously metasomatised mantle wedge source predominantly enriched by earlier TTG melts and fluids from dehydration of a subducting slab. Melting of the mantle wedge is consistent with a steeper subduction system. The late to post-kinematic high-K granite suite includes I-type calc-alkaline rocks generated through crustal partial melting of earlier TTG material. The Neoarchaean tectonic evolution of the Zimbabwe craton is shown to mark a broad continental magmatic arc (and related accretionary thrusts and sedimentary basins) linked to a subduction zone, which operated within the Limpopo– Shashe belt atf2.8–2.65 Ga. The detachment of the subducting slab led to the uprise of a hotter mantle section as the source of heat inducing crustal partial melting of juvenile TTG material to produce the high-K granite suite. URI: http://hdl.handle.net/10311/381 Files in this item: 1
Kampunzu2003Majorandtrace element.pdf (2.863Mb) -
Alemaw, B.F.; Chaoka, T.R. (Pergamon www.elsevier.com/locate/pce, NaN, 2003)[more][less]
Abstract: A distributed GIS-based hydrological model is developed using GIS and computational hydrology techniques. The model is based on water balance consideration of the surface and subsurface processes. The surface water balance processes include precipitation infiltration, overland runoff, evapo-transpiration and canopy surface interception losses on daily time steps; The subsurface process considers soil moisture accounting on a monthly basis. The model was used to estimate generated runoff from matrix of specific geo-referenced grids representing Southern Africa. All regional and seasonal dispensation of water balances have been based on standard GIS formats for storage, spatial display and interpretation of results. Considering the 1961–1990 climatic period, we have mapped the regional variation of the mean annual soil moisture (SM), actual evapo-transpiration (AET), and generated runoff (ROF) across Southern Africa or known as the SADC region. The model estimates the mean SM of the region to be about 148 mm/year. There is a wide spatial range in the distribution of SM over the region due to the fact that the absolute soil moisture is dependent on the water retention properties of the soils considered across the region. The model prediction of the mean annual AET in the region reaches a maximum of 1500 mm, with mean 420 mm. The mean annual generated runoff from the land catchment in the region is about 151 mm/year although there is a significant inter-regional variation among the SADC countries, which is a function of the variation in the vegetation cover, soil and climate variation. Lower runoff regimes are dominant in arid areas in Botswana, Namibia and south-western part of the Republic of South Africa. Higher runoff regimes are the Northern and Western Tanzania, along the east coastal portions of Mozambique, central Mozambique, western Zambia and Malawi. URI: http://hdl.handle.net/10311/492 Files in this item: 1
ALEMAW2003CONTINENTAL SCALE.pdf (623.4Kb) -
Alemaw, B.F.; Shemang, E.M.; Chaoka, T.R. (Elsevier Science Ltd, http://www.elsevier.com/locate/pce, NaN, 2004)[more][less]
Abstract: Botswana is a semi-arid country with limited recharge to groundwater resources. Groundwater however is a major source of water for domestic, industrial and agricultural uses. There is therefore the need to ensure that the groundwater resources are of drinking quality, by protecting them against pollution sources such as landfills, pit latrines, industries, agricultural pesticides and waste. In this study a preliminary assessment of vulnerability of groundwater to pollution in Kanye well field in SE Botswana is undertaken. In order to assess the vulnerability of this aquifer to pollution, soils types, mapped geology and information from 82 boreholes were input into a GIS system to classify pollution vulnerability using Theissen polygons of the study area. Results indicate that 58% of the well field area is highly or very highly vulnerable to pollution, 34% is moderately vulnerable to pollution, and only 9% has low vulnerability. Estimates of the aquifer media characteristics in areas with only a few observations or few geological logs were considered to have higher uncertainty than areas with many observations. However, the use of the polynomial estimator enabled consideration of simple uncertainty for the aquifer media characteristics and pollution vulnerability modelling process. URI: http://hdl.handle.net/10311/888 Files in this item: 1
Alemaw_PCE_2004.pdf (375.0Kb) -
Ekosse, G.; van den Heever, D.J.; de Jager, L.; Totolo, O. (Elsevier www.elsevier.com/locate/mineng, NaN, 2004)[more][less]
Abstract: This study aimed at chemically and mineralogically characterizing whole particulate air matter (PAM) occurring at the Selebi Phikwe nickel–copper (Ni–Cu) area in Botswana, and postulating its possible environmental implications.Heavy metals concentrations in PAM samples around the Selebi Phikwe Ni–Cu plant were determined by atomic absorption spectrometry and the mineral phases identified by X-ray powder diffraction technique.The particles consisted of quartz, pyrrhotite, chalcopyrite, albite and djurleite.Concentration levels of heavy metals contained in PAM samples could be related to mineral phases present.Quite significantly is the occurrence of djurleite, which has not been found in both the orebody and surrounding soils.Djurleite polymorphs formed from secondary mineralization of chalcocite and the gases H2S and SO2 released from concentration/smelting processes.Possible environmental chemistry of the whole PAM based on its mineralogy at Selebi Phikwe area is discussed. Description: Technical Note URI: http://hdl.handle.net/10311/545 Files in this item: 1
Ekosse2004Environmental Chemistry1.pdf (511.2Kb) -
Jourdan, F.; Fe´raud, G.; Bertrand, H.; Kampunzu, A.B.; Tshoso, G.; Le Gall, B.; Tiercelin, J.-J.; Capiez, P. (Elservier www.elsevier.com/locate/epsl, NaN, 2004)[more][less]
Abstract: The lower Jurassic Karoo–Ferrar magmatism represents one of the most important Phanerozoic continental flood basalt (CFB) provinces. The Karoo CFB province is dominated by tholeiitic traps and apparently radiating giant dyke swarms covering altogether ca. 3 106 km2. This study focuses on the giant N110j-trending Okavango dyke swarm (ODS) stretching over 1500 km across Botswana. This dyke swarm represents the main (failed) arm of the so-called Karoo triple junction that is generally considered as a key marker of the impingement of the Karoo starting mantle plume head. ODS dolerites yield six new plagioclase 40Ar/39Ar plateau (and miniplateau) ages ranging from 178.7F0.7 and 180.9F1.3 Ma. The distribution of the ages along a narrow Gaussian curve suggests a short period of magmatic activity centered around 179 Ma, i.e., f5 Ma younger than the emplacement age of Karoo mafic magmas in the southern part of the Karoo CFB province (f184). This age difference indicates that Karoo magmatism does not represent a short-lived event as is generally the case for most CFB but lasted at least 5Ma over the whole province. In addition, small clusters of plagioclase separated from 28 other dykes and measured by ‘‘speedy’’ step-heating experiments (with mostly two to three steps), gave either ‘‘Karoo’’ or Proterozoic ages. Integrated ages of the Proterozoic rocks range from 851F6 to 1672F7 Ma, and one plateau age (959.1F4.6 Ma) and one possibly geologically significant weightedmean age (982.7F4.0 Ma) were obtained. Proterozoic and Karoo mafic rocks are petrographically similar, but Proterozoic dykes display clear geochemical differences (e.g., TiO2 < 2.1%) with the Karoo high-Ti ODS (TiO2>2.1%). Geochemical data combined with available Ar/Ar dates allow the identification of the two groups within a total set of 77 dykes investigated: f10% of the bulk ODS dykes are Proterozoic. Thus, the Jurassic Karoo ODS dykes were emplaced along reactivated Proterozoic structures and there is no pristine Jurassic Nuanetsi triple junction as commonly proposed. This throws into doubt the validity of the ‘‘active plume head’’ Karoo CFB rift models as being responsible for the observed ‘‘triple junction’’ dyke geometry URI: http://hdl.handle.net/10311/383 Files in this item: 1
Kampunzu2004KarooTripleJunction.pdf (1.306Mb) -
Cailteux, J.L.H.; Kampunzu, A.B.; Lerouge, C.; Kaputo, A.K.; Milesi, J.P. (Elsevier www.elsevier.com/locate/jafrearsci, NaN, 2005)[more][less]
Abstract: The Neoproterozoic central African Copperbelt is one of the greatest sediment-hosted stratiform Cu–Co provinces in the world, totalling 140 Mt copper and 6 Mt cobalt and including several world-class deposits (P10 Mt copper). The origin of Cu–Co mineralisation in this province remains speculative, with the debate centred around syngenetic–diagenetic and hydrothermal-diagenetic hypotheses. The regional distribution of metals indicates that most of the cobalt-rich copper deposits are hosted in dolomites and dolomitic shales forming allochthonous units exposed in Congo and known as Congolese facies of the Katangan sedimentary succession (average Co:Cu = 1:13). The highest Co:Cu ratio (up to 3:1) occurs in ore deposits located along the southern structural block of the Lufilian Arc. The predominantly siliciclastic Zambian facies, exposed in Zambia and in SE Congo, forms para-autochthonous sedimentary units hosting ore deposits characterized by lower a Co:Cu ratio (average 1:57). Transitional lithofacies in Zambia (e.g. Baluba, Mindola) and in Congo (e.g. Lubembe) indicate a gradual transition in the Katangan basin during the deposition of laterally correlative clastic and carbonate sedimentary rocks exposed in Zambia and in Congo, and are marked by Co:Cu ratios in the range 1:15. The main Cu–Co orebodies occur at the base of the Mines/Musoshi Subgroup, which is characterized by evaporitic intertidal–supratidal sedimentary rocks. All additional lenticular orebodies known in the upper part of the Mines/Musoshi Subgroup are hosted in similar sedimentary rocks, suggesting highly favourable conditions for the ore genesis in particular sedimentary environments. Prelithification sedimentary structures affecting disseminated sulphides indicate that metals were deposited before compaction and consolidation of the host sediment. The ore parageneses indicate several generations of sulphides marking syngenetic, early diagenetic and late diagenetic processes. Sulphur isotopic data on sulphides suggest the derivation of sulphur essentially from the bacterial reduction of seawater sulphates. The mineralizing brines were generated from sea water in sabkhas or hypersaline lagoons during the deposition of the host rocks. Changes of Eh–pH and salinity probably were critical for concentrating copper–cobalt and nickel mineralisation. Compressional tectonic and related metamorphic processes and supergene enrichment have played variable roles in the remobilisation and upgrading of the primary mineralisation. There is no evidence to support models assuming that metals originated from: (1) Katangan igneous rocks and related hydrothermal processes or; (2) leaching of red beds underlying the orebodies. The metal sources are pre-Katangan continental rocks, especially the Palaeoproterozoic low-grade porphyry copper deposits known in the Bangweulu block and subsidiary Cu–Co–Ni deposits/occurrences in the Archaean rocks of the Zimbabwe craton. These two sources contain low grade ore deposits portraying the peculiar metal association (Cu, Co, Ni, U, Cr, Au, Ag, PGE) recorded in the Katangan sediment-hosted ore deposits. Metals were transported into the basin dissolved in water. The stratiform deposits of Congo and Zambia display features indicating that syngenetic and early diagenetic processes controlled the formation of the Neoproterozoic Copperbelt of central Africa. URI: http://hdl.handle.net/10311/387 Files in this item: 1
Kampunzu2005GenesisSediment.pdf (2.837Mb) -
Le Gall, B.; Tshoso, G.; Dyment, J.; Kampunzu, A.B.; Jourdan, F.; Fe´raud, G.; Bertrand, H.; Aubourg, C.; Ve´tel, W. (Elsevier www.elsevier.com/locate/jsg, NaN, 2005)[more][less]
Abstract: The structural organization of a giant mafic dyke swarm, the Okavango complex, in the northern Karoo Large Igneous Province (LIP) of NE Botswana is detailed. This N1108E-oriented dyke swarm extends for 1500 km with a maximum width of 100 km through Archaean basement terranes and Permo-Jurassic sedimentary sequences. The cornerstone of the study is the quantitative analysis of NO170 (exposed) and NO420 (detected by ground magnetics) dykes evidenced on a ca. 80-km-long section lying in crystalline host-rocks, at high-angle to the densest zone of the swarm (Shashe area). Individual dykes are generally sub-vertical and parallel to the entire swarm. Statistical analysis of width data indicates anomalous dyke frequency (few data !5.0 m) and mean dyke thickness (high value of 17 m) with respect to values classically obtained from other giant swarms. Variations of mean dyke thicknesses from 17 (N1108E swarm) to 27 m (adjoining and coeval N708E giant swarm) are assigned to the conditions hosting fracture networks dilated as either shear or pure extensional structures, respectively, in response to an inferred NNW–SSE extension. Both fracture patterns are regarded as inherited brittle basement fabrics associated with a previous (Proterozoic) dyking event. The Okavango N1108E dyke swarm is thus a polyphase intrusive system in which total dilation caused by Karoo dykes (estimated frequency of 87%) is 12.2% (6315 m of cumulative dyke width) throughout the 52-km-long projected Shashe section. Assuming that Karoo mafic dyke swarms in NE Botswana follow inherited Proterozoic fractures, as similarly applied for most of the nearly synchronous giant dyke complexes converging towards the Nuanetsi area, leads us to consider that the resulting triple junction-like dyke/fracture pattern is not a definitive proof for a deep mantle plume in the Karoo LIP. URI: http://hdl.handle.net/10311/400 Files in this item: 1
Kampunzu2005Okavangogiant.pdf (3.456Mb) -
Ringrose, S.; Huntsman-Mapila, P.; Kampunzu, A.B.; Downey, W.; Coetzee, S.; Vink, B.W.; Matheson, W.; Vanderpost, C. (Elsevier www.elsevier.com/locate/palaeo, NaN, 2005)[more][less]
Abstract: This work considers new evidence for palaeo environmental change taking place during the Pleistocene in northern Botswana. Duricrusted strandlines along the northeastern margin of Sua Pan provide palaeo-environmental data pertaining to the Makgadikgadi subbasin (MSB) with inferences regarding the larger Makgadikgadi–Okavango–Zambezi (MOZ) rift depression. Field, XRD and geochemical data show that MSB strandlines comprise calcretes (LU1 type), MgO-rich calcretes with silica (LU2 type), sil-calcrete (LU3 type) and silcrete (LU4 type). Early freshwater episodes appear to have been followed by calcrete-dominated drying phases interspersed with repeated silcretisation. Calcretisation through pan littoral sediments may have been both biogenically and environmentally induced. Calcite precipitation was in part controlled by the Mg/Ca ratio of pore water in the pan littoral zone suggesting closed basin type evaporative conditions, which were followed by a major desiccation interval. Phases of silcrete precipitation appear to be related to periods when the geochemistry of the lake littoral more closely resembled present-day Na–CO3–SO4–Cl-type brines. Silica saturated acidic, moderately saline groundwater preceded Si precipitation which took place as the pH reduced. Si mobilisation occurred (inter alia) as a result of quartz grain dissolution enhanced by diatoms, bacteria and algal growth in the moist pan littoral. SiO2-rich pore waters migrated through cracked and desiccated calcrete into areas of lower salinity and lower pH resulting in preferential calcite removal and silcrete precipitation. Approximate TL dates imply that exposed littoral sand underwent calcretisation during the drying phases of extensive palaeo-lakes which occurred prior to 110 ka, 80–90 ka and 41–43 ka. These wet periods compare fairly well with Vostok core chronologies for southern Africa. URI: http://hdl.handle.net/10311/794 Files in this item: 1
Kampunzu2006Sedimentological.pdf (3.498Mb) -
Huntsman-Mapila, P.; Kampunzu, A.B.; Ringrose, S.; Vink, B. (Elsevier www.elsevier.com/locate/sedgeo, NaN, 2005)[more][less]
Abstract: The siliciclastic sediments of the Okavango inland Delta of northwest Botswana have a modal composition of quartz arenites and result from a complex history, including transport by river and deposition in a nascent rift basin located in a desert environment with input of aeolian sands. The geochemical composition of sediments from the Okavango Delta was determined in order to constrain the role of weathering at the source and the composition of the source rocks. The chemical analyses and the interelement ratios show a broad compositional range usually encompassing the PAAS composition. The chemical index of alteration (CIA) values and the A–CN–K diagram define an evolution trend which can be interpreted using a mixing model involving a strongly weathered component which corresponds to the sedimentary fraction transported by the Okavango River and a relatively immature component which corresponds to the aeolian sand component of the Okavango sediments. Field geological data supported by geochemical ratios involving elements with affinity for mafic–ultramafic and felsic rocks such as Th/Cr, Th/Sc, La/Sc, La/Co and Eu/Eu* support a source area including mafic–ultramafic and felsic rocks, with or without intermediate rocks. The relationships between certain elements (Cr–Ni, Na2O–Al2O3, K2O–Al2O3) refine the interpretation by pointing to the existence of at least three source rock end-members, including a felsic rock source and pyroxene-rich and olivine-rich mafic–ultramafic source rocks. Proterozoic granitoid–gabbro and related volcanic and ortho-metamorphic rock complexes exposed in NW Botswana and adjacent Angola and Namibia are the source rocks of the sediment component which was mixed with aeolian sand and interacted with a variable proportion of diagenetic carbonates to produce the Okavango sediments. URI: http://hdl.handle.net/10311/382 Files in this item: 1
Kampunzu2005OkavangoDeltasediments.pdf (1.941Mb) -
Lerouge, C.; Cailteux, J.; Kampunzu, A.B.; Milesi, J.P.; Fle´hoc, C. (Elsevier www.elsevier.com/locate/jafrearsci, NaN, 2005)[more][less]
Abstract: Luiswishi is a Congo-type Neoproterozoic sediment-hosted stratiform Cu–Co ore deposit of the Central Africa Copperbelt, located northwest of Lubumbashi (DRC). The ores form two main Cu–Co orebodies hosted by the Mines Subgroup, one in the lower part of the Kamoto Formation and the other at the base of the Dolomitic Shales Formation. Sulphides occur essentially as early parallel layers of chalcopyrite and carrolite, and secondarily as late stockwork sulphides cross-cutting the bedding and the early sulphide generation. Both types of stratiform and stockwork chalcopyrite and carrolite were systematically analyzed for sulphur isotopes, along the lithostratigraphic succession of the Mine Series. The quite similar d34S values of stratiform sulphides and late stockwork sulphides suggest an in situ recrystallization or a slight remobilization of stockwork sulphides without attainment of isotopic equilibrium between different sulphide phases (chalcopyrite and carrolite). The distribution of d34S values ( 14.4& to +17.5&) combined with the lithology indicates a strong stratigraphic control of the sulphur isotope signature, supporting bacterial sulphate reduction during early diagenesis of the host sediments, in a shallow marine to lacustrine environment. Petrological features combined with sulphur isotopic data of sulphides at Luiswishi and previous results on nodules of anhydrite in the Mine Series indicate a dominant seawater/lacustrine origin for sulphates, precluding a possible hydrothermal participation. The high positive d34S values of sulphides in the lower orebody at Luiswishi, hosted in massive chloritic–dolomitic siltite (known as Grey R.A.T.), fine-grained stratified dolostone (D.Strat.) and silicified-stromatolitic dolomites alternating with chloritic–dolomitic silty beds (R.S.F.), suggest that they were probably deposited during a period of regression in a basin cut off from seawater. The variations of d34S values (i.e. the decrease of d34S values from the Kamoto Formation to the overlying Dolomitic Shales and then the slight increase from S.D.2d to S.D.3a and S.D.3b members) are in perfect agreement with the inferred lithological and transgressive–regressive evolution of the ore-hosting sedimentary rocks [Cailteux, J., 1994. Lithostratigraphy of the Neoproterozoic Shaba-type (Zaire) Roan Supergroup and metallogenesis of associated stratiform mineralization. In: Kampunzu A.B., Lubala, R.T. (Eds.), Neoproterozoic Belts of Zambia, Zaire and Namibia. Journal of African Earth Sciences 19, 279–301]. URI: http://hdl.handle.net/10311/390 Files in this item: 1
Kampunzu2005SulpherIsotope.pdf (1.156Mb) -
Cailteux, J.L.H.; Kampunzu, A.B.H.; Batumike, M.J. (Elsevier www.elsevier.com/locate/jafrearsci, NaN, 2005)[more][less]
Abstract: The Neoproterozoic Katangan R.A.T. ("Roches Argilo-Talqueuses") Subgroup is a sedimentary sequence composed of red massive to irregularly bedded terrigenous-dolomitic rocks occurring at the base of the Katangan succession in Congo. Red R.A.T. is rarely exposed in a continuous section because it was affected by a major layer-parallel de´collement during the Lufilian thrusting. However, in a number of thrust sheets, Red R.A.T. is in conformable sedimentary contact with Grey R.A.T which forms the base of the Mines Subgroup. Apart from the colour difference reflecting distinct depositional redox conditions, lithological, petrographical and geochemical features of Red and Grey R.A.T. are similar. A continuous sedimentary transition between these two lithological units is shown by the occurrence of variegated to yellowish R.A.T. The D. Strat. "Dolomies Stratifie´es" formation of the Mines Subgroup conformably overlies the Grey R.A.T. In addition, a transitional gradation between Grey R.A.T. and D. Strat. occurs in most Cu–Co mines in Katanga and is marked by interbedding of Grey R.A.T.-type and D. Strat.-type layers or by a progressive petrographic and lithologic transition from R.A.T. to D. Strat. Thus, there is an unquestionable sedimentary transition between Grey R.A.T. and D. Strat. and between Grey R.A.T. and Red R.A.T. The R.A.T. Subgroup stratigraphically underlies the Mines Subgroup and therefore R.A.T. cannot be comprised of syn-orogenic sediments deposited upon the Kundelungu (formerly ‘‘Upper Kundelungu’’) Group as suggested by Wendorff (2000). As a consequence, the Grey R.A.T. Cu–Co mineralisation definitely is part of the Mines Subgroup Lower Orebody, and does not represent a distinct generation of stratiform Cu–Co sulphide mineralisation younger than the Roan orebodies. URI: http://hdl.handle.net/10311/391 Files in this item: 1
Kampunzu2005Lithostratigraphic.pdf (1.922Mb) -
Milesi, J.P.; Toteu, S.F.; Deschamps, Y.; Feybesse, J.L.; Lerouge, C.; Cocherie, A.; Penaye, J.; Tchameni, R.; Moloto-A-Kenguemba, G.; Kampunzu, H.A.B.; Nicol, N.; Duguey, E.; Leistel, J.M.; Saint-Martin, M.; Ralay, F.; Heinry, C.; Bouchot, V.; Mbaigane, J.C. Doumnang; Kula, V. Kanda; Chene, F.; Monthel, J.; Boutin, P.; Cailteux, J. (Elsevier www.elsevier.com/locate/jafrearsci, NaN, 2006)[more][less]
Abstract: This paper is prepared within the frameworks of IGCP Project 470 and the associated BRGM scientific project ‘‘Africa 1999–2004’’ to accompany the 1:4,000,000 scale map ‘‘Geology and major ore deposits of Central Africa, presented at the 20th Colloquium of African Geology in Orleans in June 2004. It incorporates geological and metallogenic data from eight countries in Central Africa (Angola, Cameroon, Chad, Central African Republic, Congo Brazzaville, Democratic Republic of Congo (DRC), Equatorial Guinea and Zambia). The map is a harmonised and geo-referenced preliminary map, based on a GIS at 1:2,000,000 scale, and focusses on the spatial and temporal distribution of selected major deposits. URI: http://hdl.handle.net/10311/384 Files in this item: 1
Kampunzu2006MajorOreDeposits.pdf (2.307Mb) -
Jourdan, F.; Fe´raud, G.; Bertrand, H.; Watkeys, M.K.; Kampunzu, A.B.; Le Gall, B. (Elsevier www.elsevier.com/locate/epsl, NaN, 2006)[more][less]
Abstract: Continental flood basalts consist of vast quantities of lava, sills and giant dyke swarms that are associated with continental break-up. The commonly radiating geometry of dyke swarms in these provinces is generally interpreted as the result of the stress regime that affected the lithosphere during the initial stage of continental break-up or as the result of plume impact. On the other hand, structures in the basement may also control dyke orientations, though such control has not previously been documented. In order to test the role of pre-dyke structures, we investigated four major putative Karoo-aged dyke swarms that taken together represent a giant radiating dyke swarm (the so-called btriple-junctionQ) ascribed to the Jurassic Karoo continental flood basalt (N3 106 km2; southern Africa). One of the best tests to discriminate between neoformed and inherited dyke orientation is to detect Precambrian dykes in the Jurassic swarms. Accordingly, we efficiently distinguished between Jurassic and Precambrian dykes using abbreviated low resolution, 40Ar/39Ar incremental heating schedules. Save-Limpopo dyke swarm samples (n =19) yield either apparent Proterozoic (728–1683 Ma) or Mesozoic (131–179 Ma) integrated ages; the Olifants River swarm (n =20) includes only Proterozoic (851–1731 Ma) and Archaean (2470–2872 Ma) dykes. The single age obtained on one N–S striking dyke (1464 Ma) suggests that the Lebombo dyke swarm includes Proterozoic dykes in the basement as well. These dates demonstrate the existence of pre-Karoo dykes in these swarms as previously hypothesized without supporting age data. In addition, aeromagnetic and air-photo interpretations indicate that: (1) dyke emplacement was largely controlled by major discontinuities such as the Zimbabwe and Kaapvaal craton boundaries, the orientation of the Limpopo mobile belt, and other pre-dyke structures including shear zones and (2) considering its polygenetic, pre-Mesozoic origin, the Olifants River dyke swarm cannot be considered part of the Karoo magmatic event. This study, along with previous results obtained on the Okavango dyke swarm, shows that the apparent btriple junctionQ formed by radiating dyke swarms is not a Jurassic structure; rather, it reflects weakened lithospheric pathways that have controlled dyke orientations over hundreds of millions of years. One consequence is that the btriple-junctionQ geometry can no longer be unambiguously used as a mantle plume marker as previously proposed, although it does not preclude the possible existence of a mantle plume. More generally, we suggest that most Phanerozoic dyke swarms (including triple junctions) related to continental flood basalts were probably controlled in part by pre-existing lithospheric discontinuities. URI: http://hdl.handle.net/10311/386 Files in this item: 1
Kampunzu2006BasementControl.pdf (2.119Mb) -
Mapeo, R.B.M.; Armstrong, R.A.; Kampunzu, A.B.; Modisi, M.P.; Ramokate, L.V.; Modie, B.N.J. (Elsevier www.elsevier.com/locate/epsl, NaN, 2006)[more][less]
Abstract: The Segwagwa Group of southeastern Botswana, a correlate of the Pretoria Group of the Transvaal Supergroup of South Africa, consists of a major sequence of siliciclastic sedimentary rocks, minor carbonates and basaltic to andesitic lavas and tuffs straddling the Western and Central Domains of the Kaapvaal Craton. The Segwagwa Group unconformably overlies the Taupone Dolomite Group, a correlative of the South African Chuniespoort/Ghaap Groups of the Transvaal Supergroup. SHRIMP U–Pb analyses of 123 detrital zircons from the top, middle and bottom of the Segwagwa Group sedimentary rocks include 96 concordant to nearconcordant zircons defining three main age groups: >3.0–2.9 Ga (n=12), 2.8–2.5 Ga (n=27) and 2.45–2.20 Ga (n=57). The ≥2.90 Ga zircons were sourced from granitoids emplaced before and around 2915±12 Ma and are related to the amalgamation of the Western, Northern and Central Domains of the Kaapvaal Craton. Concordant zircons with a mean age of 2781±8 Ma originate from the Gaborone Igneous Complex. The detrital zircons in the range 2.7–2.5 Ga were likely sourced from the Kalahari continental fragment made up of the Kaapvaal Craton, Limpopo Belt and the Zimbabwe Craton, specifically from the Limpopo Belt and/or the Zimbabwe Craton where igneous rocks in this age range are widespread. The igneous sources for the Palaeoproterozoic (ca. 2.45–2.20 Ga) zircons are difficult to identify since igneous rocks in that age are not widely known or documented by reliable dates in the Kalahari Craton. The youngest zircons of ca. 2.2 Ga occur in all the sandstones and form the main group (N90%) in the sample from the top of the Segwagwa Group. The youngest detrital zircon of 2193±20 Ma sets the maximum time of deposition of the Segwagwa Group. Published data suggest that the minimum deposition age of Chuniespoort/Ghaap Group sedimentary rocks is 2431±31 Ma [D.R. Nelson, Compilation of SHRIMP U-Pb zircon Geochronological Data, 1996 Record 1997/2, pp. 189, Western Australia Geological Survey, 1997.]. Therefore, the unconformity between the Lower and Upper Transvaal represents a ∼200 Ma hiatus, and the lithostratigraphic units on the two sides of the unconformity should not be grouped in the same supergroup. Detrital zircon ages suggest that the time of deposition of the Segwagwa/Pretoria Group which ranges from ca. 2.40 to 2.20 Ga is coeval with the Palaeoproterozoic global glacial deposits in North America, Australia and Fennoscandia; and with sedimentary rocks from the Palaeoproterozoic Magondi Belt. Therefore, the Segwagwa/Pretoria Group and the Magondi metasedimentary succession were deposited during the first global glacial period, are possibly related to the same geodynamic cycle, and should be part of the same supergroup. URI: http://hdl.handle.net/10311/742 Files in this item: 1
Mapeo2006Transvaal Groups.pdf (1.993Mb) -
Mapeo, R.B.M.; Ramokate, L.V.; Corfu, F.; Davis, D.W.; Kampunzu, A.B. (Elsevier Ltd. www.elsevier.com/locate/jafrearsci, NaN, 2006)[more][less]
Abstract: The Okwa Basement Complex crops out at the northwestern edge of the Kaapvaal craton within the Okwa Inlier, an isolated exposure of Precambrian basement in the Kalahari Desert. New U–Pb zircon dating was performed on all the major Palaeoproterozoic lithologies of the complex. Results are 2055.3 ± 1.3 Ma for augen gneiss, 2056.3 ± 1.3 Ma for foliated monzogranite and 2057 ± 2 Ma for microgranite. A meta-rhyolite gives an age of 2055 ± 4 Ma, based on one concordant zircon, and contains an inherited zircon with an age of 2101 ± 4 Ma. All precisely dated rocks are indistinguishable in age at 2056 ± 2 Ma. This age can be broadly correlated with Palaeoproterozoic geologic events in the Magondi belt at the northwest margin of the Zimbabwe craton and the Triangle Shear Zone in the Limpopo belt. However, the most precise correlation is with the Bushveld Complex, whose age is indistinguishable from that of the Okwa Basement Complex. This suggests a link between marginal and intra-cratonic Bushveld-age magmatism on the Kaapvaal craton. URI: http://hdl.handle.net/10311/272 Files in this item: 1
The Okwa basement complex.pdf (5.655Mb) -
Huntsman-Mapila, P.; Ringrose, S.; Mackay, A.W.; Downey, W.S.; Modisi, M.; Coetzee, S.H.; Tiercelin, J.-J.; Kampunzu, A.B.; Vanderpost, C. (Elsevier, www.sciencedirect.com, NaN, 2006)[more][less]
Abstract: Sediment samples from a continuous 4.6m profile in the dry bed of Lake Ngami in NW Botswana were analysed for geochemistry and dated using both 14C and TL methods. Certain units in the profile were found to be diatom rich and these, with the geochemical results, were used as indicators of high and low lake levels within the basin. The Lake Ngami sediments contain a high proportion of SiO2 (51–92.5 wt%, avg. 72.4 wt%) and variable levels of Al2O3 (2.04–17.2 wt%, avg. 8.88 wt%). Based on elevated Al2O3 and organic matter (LOIorgC) results, lacustrine conditions occurred at ca. 42 ka until 40 ka and diatom results suggest that relatively deep but brackish conditions prevailed. At 40 ka, the lacustrine sedimentary record was terminated abruptly, possibly by tectonic activity. At ca. 19 ka, shallow, aerobic, turbulent conditions were prevalent, but lake levels were at this time increasing to deeper water conditions up until ca. 17 ka. This period coincides with the Late Glacial Maximum, a period of increased aridity in the central southern Africa region. Generally, increasing Sr/Ca ratios and decreasing LOIorgC and Al2O3, from ca. 16 to 5 ka, suggest decreasing inflow into the basin and declining lake levels. Based on the enrichment of LREE results, slightly alkaline conditions prevailed at ca. 12 ka. Diatom results also support shallow alkaline conditions around this time. These lake conditions were maintained primarily by local rainfall input as the region experienced a warmer, wetter phase between 16 and 11 ka. Lake levels rose rapidly by 4 ka, probably in response to enhanced rainfall in the Angolan catchment. These results indicate that lake levels in the Lake Ngami basin are responding to rainfall changes in the Angolan catchment area and local rainfall. The results confirm that the present-day anti-phase rainfall relationship between southern Africa and regions of equatorial Africa was extant during the late Quaternary over the Angolan highlands and NW Botswana. URI: http://hdl.handle.net/10311/891 Files in this item: 1
Modisi2006SedimentaryRecord.pdf (1.674Mb)
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