Browsing Chemistry by Subject "Prenylated chalcones"

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Dinklagins A, B and C: three prenylated flavonoids and other constituents from the twigs of Dorstenia dinklagei

Ngadjui, B.; Dongo, E.; Abegaz, B.; Fotso, S.; Tamboue, H. (Elsevier Science Ltd. www.elsevier.com/locate/phytochem, NaN, 2002)

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Abstract:

Three prenylated flavonoids, dinklagins A, B and C identified, respectively, as ( )-6-(3,3-dimethylallyl)-7-hydroxy-6000, 6000-dimethylchromeno-( 40,30,2000,3000)-flavanone, (+)-5,40,500x-trihydroxy-600,600-dimethylchromano-(7,6,200,300)-flavone and (+)6-(2x-hydroxy- 3-methyl-3-butenyl)-5,7,40-trihydroxyflavone were isolated from the twigs of Dorstenia dinklagei together with the known 6-prenylapigenin, 4-hydroxylonchocarpin, stipulin and 5,40-dihydroxy-600,600-dimethylchromano-(7,6,200,300)-flavone. Their structures were determined on the basis of spectral data and by comparison with data reported in the literature and with authentic specimens for known compounds.

URI:

http://hdl.handle.net/10311/262

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Dinklagins A, B and C three prenylated.pdf (3.292Mb)

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Diprenylated chalcones and other constituents from the twigs of Dorstenia barteri var. subtriangularis

Ngameni, B.; Ngadjui, B.; Folefoc, G.; Watchueng, J.; Abegaz, B. (Elsevier Ltd; www.elsevier.com/locate/phytochem, NaN, 2003)

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Abstract:

The twigs of Dorstenia barteri var. subtriangularis yielded three diprenylated chalcones: ( )-3-(3,3-dimethylallyl)-50-(2-hydroxy-3- methylbut-3-enyl)-4,20,40-trihydroxychalcone, (+)-3-(3,3-dimethylallyl)-40,50-[2000-(1-hydroxy-1-methylethyl)-dihydrofurano]-4,20- dihydroxychalcone and 3,4-(600,600-dimethyldihydropyrano)-40,50-[2000,-(1-hydroxy-1-methylethyl)-dihydrofurano]-20-hydroxychalcone for which the names bartericins A, B and C, respectively, are proposed. Stipulin, b-sitosterol and its 3-b-D-glucopyranosyl derivative were also isolated. The structures of these secondary metabolites were determined on the basis of spectroscopic analysis, especially, NMR spectra in conjunction with 2D experiments, COSY, HMQC and HMBC. The structural relationship of bartericins B and C was further established by the chemical cyclization of one to the other.

URI:

http://hdl.handle.net/10311/258

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Diprenylated chalcones and other.pdf (3.479Mb)

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Prenylated chalcones, flavone and other constituents of the twigs of Dorstenia angusticornis and Dorstenia barteri var. subtriangularis

Ngadjui, B.; Watchueng, J.; Keumedjio, F.; Ngameni, B.; Simo, I.; Abegaz, B. (Elsevier Ltd. www.elsevier.com/locate/phytochem, NaN, 2004)

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Abstract:

The twigs of Dorstenia angusticornis and Dorstenia barteri var. subtriangularis yielded 16 compounds. Two novel diprenylated chalcones: 3,50-di-(2-hydroxy-3-methylbut-3-enyl)-4,20,40-trihydroxychalcone, 3, 4-(2,2-dimethylpyrano)-30-(2-hydroxy-3-methylbut- 3-enyl)-20,40-dihydroxychalcone and the known stipulin were isolated from both species. 3-(2-Hydroxy-3-methylbut-3-enyl)- 50-(3,3-dimethylallyl)-4,20,40-trihydroxychalcone and the known compounds: 4-hydroxylonchocarpin, kanzonol B, bartericins A, B, C and 30-(2-hydroxy -3-methylbut-3-enyl)-4,20,40-trihydroxychalcone were isolated from D. barteri while the known compounds: gancaonin Q, paratocarpins C, F, and lupeol were obtained from Dorstenia angusticornis. b-Sitosterol and its b-D-glucopyranoside were isolated from both species. Structures of these secondary metabolites were established using spectroscopic analysis, especially, NMR spectra in conjunction with 2D experiments, COSY, HMQC and HMBC.

URI:

http://hdl.handle.net/10311/253

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license.txt (1.998Kb)

Prenylated chalcones, flavone.pdf (3.563Mb)

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Browsing Chemistry by Subject "Prenylated chalcones"

Browsing Chemistry by Subject "Prenylated chalcones"

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