Browsing Chemistry by Subject "Okavango Delta"
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Daka, P.S.; Obuseng, V.C.; Torto, N.; Huntsman-Mapila, P. (Water SA Pretoria; Water Research Commission; http://www.wrc.org.za/, October NaN, 2006)[more][less]
Abstract: Deltamethrin concentrations were determined in 35 sediment samples collected from three different habitats: channel, lagoon and pool sites from Xakanaxa in the Okavango Delta, NW Botswana. The samples were Soxhlet-extracted in acetone to extract deltamethrin residues and subsequently cleaned-up with silica gel 60. The final determination was carried out with a gas chromatograph equipped with an electron capture detector (GC-ECD). The sample work-up and determination gave deltamethrin recoveries of 54 to 97%, and detection limits of 0.004 mg/kg dw. The concentration of deltamethrin residues in the sediment samples collected from the three sprayed areas in the Okavango delta ranged between 0.013 and 0.291 mg/kg dw, with the highest concentrations observed in samples obtained from the pool sites. Analysis of samples for organic matter content showed percentage total organic carbon (% TOC) ranging between 0.19% and 8.21%, with samples collected from the pool having the highest total organic carbon. The concentrations of deltamethrin residues and the % TOC in sediment samples showed a similar trend with the highest levels recorded in the pool samples. These data confirmed that a simple method based on GC-ECD, after Soxhlet extraction, was robust enough to enable quantification of deltamethrin in the sediments, because comparable results were obtained with a more sophisticated system consisting of a GC coupled to a mass spectrometer with a time of flight (TOF) analyser. URI: http://hdl.handle.net/10311/140 Files in this item: 2
dakaetal.pdf (463.1Kb)license.txt (1.998Kb) -
Mubyana-John, T.; Wutor, V.C.; Yeboah, S.O.; Ringrose, S. (Academic Journals. http://www.academicjournals.org/SRE, NaN, 2007)[more][less]
Abstract: The influence of wild fires on microbial community structure, soil organic matter, sulphur oxidising and nitrifying microbial populations in the floodplains of the Okavango Delta of Botswana was assessed. Microbial community structure was assessed by phospholipids ester-linked fatty acids (PLFA) quantification while microbial sulphur oxidisers were assessed by Most Probable Number (MPN). Community structure assessment showed that burning shifted the microbial community structure from single cellular bacteria being the dominant groups to filamentous fungi and actinomycetes being the most dominant groups. Generally burning increased the fungal component (18:2 w6) matrix from 3.40 to 8.35 while the actinomycetes and sulphur reducing bacterial (10 Me 16:0) component also increased from 1.02 to 1.70 mostly in the floodplains. Generally, the organic matter content declined with burning. However, the influence of burning on soil pH was non conclusive. Soil microbial biomass carbon increased slightly after the fire. The number of heterotrophic and nitrite-oxidizing and sulphur reducing bacteria increased. Overall, these results indicate that burning significantly alters the microbial community structure as large above ground losses of nutrients during and after burning often results in low quantities of nutrients released into the soil. URI: http://hdl.handle.net/10311/349 Files in this item: 1
Fire and.pdf (2.461Mb)
Now showing items 1-2 of 2