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dc.contributor.author Lerouge, C.
dc.contributor.author Cailteux, J.
dc.contributor.author Kampunzu, A.B.
dc.contributor.author Milesi, J.P.
dc.contributor.author Fle´hoc, C.
dc.date.accessioned 2009-10-15T13:42:37Z
dc.date.available 2009-10-15T13:42:37Z
dc.date.issued 2005
dc.identifier.citation Lerouge, C. et al (2005) Sulphur isotope constraints on formation conditions of the Luiswishi ore deposit, Democratic Republic of Congo (DRC), Journal of African Earth Sciences, Vol. 42, pp. 173–182 en_US
dc.identifier.issn 1464-343X
dc.identifier.uri http://hdl.handle.net/10311/390
dc.description.abstract Luiswishi is a Congo-type Neoproterozoic sediment-hosted stratiform Cu–Co ore deposit of the Central Africa Copperbelt, located northwest of Lubumbashi (DRC). The ores form two main Cu–Co orebodies hosted by the Mines Subgroup, one in the lower part of the Kamoto Formation and the other at the base of the Dolomitic Shales Formation. Sulphides occur essentially as early parallel layers of chalcopyrite and carrolite, and secondarily as late stockwork sulphides cross-cutting the bedding and the early sulphide generation. Both types of stratiform and stockwork chalcopyrite and carrolite were systematically analyzed for sulphur isotopes, along the lithostratigraphic succession of the Mine Series. The quite similar d34S values of stratiform sulphides and late stockwork sulphides suggest an in situ recrystallization or a slight remobilization of stockwork sulphides without attainment of isotopic equilibrium between different sulphide phases (chalcopyrite and carrolite). The distribution of d34S values ( 14.4& to +17.5&) combined with the lithology indicates a strong stratigraphic control of the sulphur isotope signature, supporting bacterial sulphate reduction during early diagenesis of the host sediments, in a shallow marine to lacustrine environment. Petrological features combined with sulphur isotopic data of sulphides at Luiswishi and previous results on nodules of anhydrite in the Mine Series indicate a dominant seawater/lacustrine origin for sulphates, precluding a possible hydrothermal participation. The high positive d34S values of sulphides in the lower orebody at Luiswishi, hosted in massive chloritic–dolomitic siltite (known as Grey R.A.T.), fine-grained stratified dolostone (D.Strat.) and silicified-stromatolitic dolomites alternating with chloritic–dolomitic silty beds (R.S.F.), suggest that they were probably deposited during a period of regression in a basin cut off from seawater. The variations of d34S values (i.e. the decrease of d34S values from the Kamoto Formation to the overlying Dolomitic Shales and then the slight increase from S.D.2d to S.D.3a and S.D.3b members) are in perfect agreement with the inferred lithological and transgressive–regressive evolution of the ore-hosting sedimentary rocks [Cailteux, J., 1994. Lithostratigraphy of the Neoproterozoic Shaba-type (Zaire) Roan Supergroup and metallogenesis of associated stratiform mineralization. In: Kampunzu A.B., Lubala, R.T. (Eds.), Neoproterozoic Belts of Zambia, Zaire and Namibia. Journal of African Earth Sciences 19, 279–301]. en_US
dc.language.iso en en_US
dc.publisher Elsevier www.elsevier.com/locate/jafrearsci en_US
dc.subject Central Africa Copperbelt en_US
dc.subject Luiswishi en_US
dc.subject DRC en_US
dc.subject Mineralogy en_US
dc.subject Sulphur isotopes en_US
dc.title Sulphur isotope constraints on formation conditions of the Luiswishi ore deposit, Democratic Republic of Congo (DRC) en_US
dc.type Published Article en_US


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