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dc.contributor.author Bwire, R N
dc.contributor.author Majinda, R R
dc.contributor.author Masesane, I B
dc.contributor.author Steel, P G
dc.date.accessioned 2009-03-30T06:39:18Z
dc.date.available 2009-03-30T06:39:18Z
dc.date.issued 2009
dc.identifier.citation Bwire, R N et al. (2009). From nature, through chemical synthesis, toward use in agriculture: Oryzoxymycin case study, Pure Appl. Chem., vol. 81 (1), pp. 105–112 en
dc.identifier.issn 1365-3075
dc.identifier.uri http://hdl.handle.net/10311/301
dc.description.abstract The Diels–Alder adducts of ethyl (E)-3-nitroacrylate and furan provided a common and versatile template for the stereocontrolled synthesis of an isomer of the natural product oryzoxymycin and polyhydroxylated cyclohexyl β-amino acid derivatives. The strategy for the synthesis of the polyhydroxylated cyclic β-amino acid derivatives involved base-induced fragmentation of the oxanorbornene skeleton and face selective oxidation reactions. A Pd-catalyzed transfer hydrogenation reaction in the presence of organic acids is also described. This reaction is amenable to being enantioselective through use of optical pure chiral organic acids. en
dc.language.iso en en
dc.publisher International Union of Pure and Applied Chemistry. http://stage.iupac.org/publications/pac/ en
dc.subject oryzoxymycin en
dc.subject Diels–Alder reaction en
dc.subject nitroacrylate en
dc.subject epoxidation en
dc.subject transfer hydrogenation en
dc.title From nature, through chemical synthesis, toward use in agriculture: Oryzoxymycin case study en
dc.type Published Article en


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