Browsing Research articles (ORI) by Author "Huntsman-Mapila, P."
Now showing items 1-9 of 9
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Characterization of arsenic occurrence in the water and sediments of the Okavango Delta, NW BotswanaHuntsman-Mapila, P.; Mapila, T.; Letshwenyo, M.; Wolski, P.; Hemond, C. (Elsevier Science B.V. Amsterdam; http://www.elsevier.com/wps/find/journaldescription.cws_home/768/description#description, NaN, 2006)[more][less]
Abstract: Detailed chemical analyses were performed on surface water, groundwater and sediment samples collected from the Okavango Delta between February and November 2003 in order to examine the distribution and geochemistry of naturally occurring As in the area. Surface water in the Okavango Delta, which is neutral to slightly acidic and has high dissolved organic C (DOC), was found to be slightly enriched in As when compared to a global value for stream water. Of the 20 new borehole analyses from this project, six were found to have values exceeding 10 ug/L. the current World Health Organization provisional guideline value for As. The results from field speciation indicate that As(III) is slightly more predominant than As(V). There is a positive correlation between As and pH and between As and DOC in the groundwater samples. For the sediment samples, there is a positive correlation between As and Co. As and Fe. As and loss on ignition (LOI) and between As and the percent fines in the sample. Reductive dissolution of oxides and hydroxides in the sediments with organic C as an electron acceptor is the likely mechanism for the release of As from the sediments into the groundwater. URI: http://hdl.handle.net/10311/135 Files in this item: 2
huntsman-mapila_app_geochem.pdf (3.170Mb)license.txt (1.998Kb) -
Huntsman-Mapila, P.; Kampunzu, A.B.; Vink, B.; Ringrose, S. (Elsevier; http://www.elsevier.com/wps/find/journaldescription.cws_home/503361/description#description, NaN, 2005)[more][less]
Abstract: [Please note that chemical formulae do not display properly]:The siliciclastic sediments of the Okavango inland Delta of northwest Botswana have a modal composition of quartz arenites and result from a complex history, including transport by river and deposition in a nascent rift basin located in a desert environment with input of aeolian sands. The geochemical composition of sediments from the Okavango Delta was determined in order to constrain the role of weathering at the source and the composition of the source rocks. The chemical analyses and the interelement ratios show a broad compositional range usually encompassing the PAAS composition. The chemical index of alteration (CIA) values and the A-CN-K diagram define an evolution trend which can be interpreted using a mixing model involving a strongly weathered component which corresponds to the sedimentary fraction transported by the Okavango River and a relatively immature component which corresponds to the aeolian sand component of the Okavango sediments. Field geological data supported by geochemical ratios involving elements with affinity for mafic-ultramafic and felsic rocks such as Th/Cr, Th/Sc, La/Sc, La/Co and Eu/Eu* support a source area including mafic-ultramafic and felsic rocks, with or without intermediate rocks. The relationships between certain elements (Cr-Ni, Na2O-Al2O3, K2O- Al2O3) refine the interpretation by pointing to the existence of at least three source rock end-members, including a felsic rock source and pyroxene-rich and olivine-rich mafic-ultramafic source rocks. Proterozoic granitoid-gabbro and related volcanic and ortho-metamorphic rock complexes exposed in NW Botswana and adjacent Angola and Namibia are the source rocks of the sediment component which was mixed with aeolian sand and interacted with a variable proportion of diagenetic carbonates to produce the Okavango sediments. Description: This paper was a contribution to the SAFARI 2000 Research Project. URI: http://hdl.handle.net/10311/153 Files in this item: 2
huntsman_mapila_sedgeo.pdf (6.089Mb)license.txt (1.998Kb) -
Daka, P.S.; Obuseng, V.C.; Torto, N.; Huntsman-Mapila, P. (South African Water Research Commission http://www.wrc.org.za, NaN, 2006)[more][less]
Abstract: Deltamethrin concentrations were determined in 35 sediment samples collected from three different habitats: channel, lagoon and pool sites from Xakanaxa in the Okavango Delta, NW Botswana. The samples were Soxhlet-extracted in acetone to extract deltamethrin residues and subsequently cleaned-up with silica gel 60. The final determination was carried out with a gas chromatograph equipped with an electron capture detector (GC-ECD). The sample work-up and determination gave deltamethrin recoveries of 54 to 97%, and detection limits of 0.004 mg/kg dw. The concentration of deltamethrin residues in the sediment samples collected from the three sprayed areas in the Okavango delta ranged between 0.013 and 0.291 mg/kg dw, with the highest concentrations observed in samples obtained from the pool sites. Analysis of samples for organic matter content showed percentage total organic carbon (% TOC) ranging between 0.19% and 8.21%, with samples collected from the pool having the highest total organic carbon. The concentrations of deltamethrin residues and the % TOC in sediment samples showed a similar trend with the highest levels recorded in the pool samples. These data confirmed that a simple method based on GC-ECD, after Soxhlet extraction, was robust enough to enable quantification of deltamethrin in the sediments, because comparable results were obtained with a more sophisticated system consisting of a GC coupled to a mass spectrometer with a time of flight (TOF) analyser. URI: http://hdl.handle.net/10311/650 Files in this item: 1
Daka_WSA_2006.pdf (1.231Mb) -
Ringrose, S.; Vanderpost, C.; Matheson, W.; Wolski, P.; Huntsman-Mapila, P.; Murray-Hudson, M.; Jellema, A. (Elsevier Ltd; www.elsevier.com/locate/jaridenv, January NaN, 2007)[more][less]
Abstract: This work seeks to determine whether riparian woody plant variables respond to drying and salinity regimes in the semi-arid distal Okavango Delta, northern Botswana. Structural and compositional variables were obtained from 47 field sites. Mapping using satellite imagery illustrated differences in the character of riparian zones in terms of species composition and provided data on flood frequency. Salinity data plots show increases downstream. Results imply that woody plant variables respond to desiccation-driven change due to water-table lowering (reduced recharge) and increased salinization through distinct changes in tree and shrub height, plant density and species richness. In the wetter, intermediate distributaries, key biotic indicators of ecosystem change comprise structural variables such as decreases in canopy cover per cent and tree height and increases of shrub height, which are indicative of mainly ground-water declines. Biotic indicators in the less frequently flooded receiver channels comprise plant density and species richness increases involving mainly brackish ground-water-tolerant and dryland species which are indicative of both ground-water declines and/or salinization. These indicators could provide useful parameters for use in long- and short-term monitoring aimed at assessing desiccation-driven change in different parts of the Okavango Delta and possibly other semi-arid wetlands. The indicators are important as a less-expensive alternative to drilling as a means of verifying ground-water declines and/or salinization. URI: http://hdl.handle.net/10311/161 Files in this item: 2
license.txt (1.998Kb)Ringrose_et_al_JAE_07.pdf (1.322Mb) -
Wolski, P.; Murry-Hudson, M.; Fernkvist, P.; Liden, A.; Huntsman-Mapila, P.; Ramberg, L. (Botswana Society, NaN, 2005)[more][less]
Abstract: Groundwater under islands in the Okavango Delta is a known sink of inorganic dissolved minerals, preventing salinisation of this virtually enclosed evaporation-dominated hydrological system. The Okavango Delta is an oligotrophic, yet very productive system, and it is important to understand sources, pathways and recycling of nutrients in order to fully comprehend its ecology. In order to investigate the role of islands as nutrient sinks, concentrations of nitrogen and phosphorus, as well as major inorganic ions were measured in island and floodplain groundwater. The electrical conductivity was found to be up to 50 times higher in the island centre groundwater than in the surrounding floodplain groundwater. The amount of total phosphorus was found to be up to 400 times higher and total nitrogen up to five times higher in the interior of the island than in the surrounding floodplain. These show that major nutrients are, like other inorganic ions, accumulated under islands. Importantly, the ratio of nitrogen to phosphorus was 5:1 in floodplain water and water in island fringe soils, but 1:4 in island centres. his indicates an intensive removal of nitrogen along the floodplain-island groundwater flow path by the floodplain fringe and riparian biota, resulting in a relative enrichment in P. URI: http://hdl.handle.net/10311/950 Files in this item: 1
Wolski 2005 Islands.pdf (1.469Mb) -
Lezine, A-M.; von Grafenstein, U.; Andersen, N.; Belmecheri, S.; Bordon, A.; Caron, B.; Cazet, J.-P.; Erlenkeuser, H.; Fouache, E.; Grenier, C.; Huntsman-Mapila, P.; Hureau-Mazaudier, D.; Manelli, D.; Mazaud, A.; Robert, C.; Sulpizio, R.; Tiercelin, J.-J.; Zanchetta, G.; Zeqollari, Z. (Elsevier, January 11, 2010)[more][less]
Abstract: Multi-proxy analyses on core JO2004-1 recovered from Lake Ohrid (40°55.000 N, 20°40.297E, 705 m a.s.l.) provide the first environmental and climate reconstruction in a mountainous area in Southern Europe over the last 140,000 years. The response of both lacustrine and terrestrial environments to climate change has been amplified by the peculiar geomorphological and hydrological setting, with a steep altitudinal gradient in the catchment and a karstic system feeding the lake. The karstic system was active during interglacials, leading to high carbonate production in the lake, and blocked during glacials as a result of extremely cold climate conditions with permafrost in the mountains. At the Riss–Eemian transition (Termination 2) the increase in lacustrine productivity predated forest expansion by about 10,000 years. In contrast, the Late Glacial–Holocene transition (Termination 1) was characterized by the dramatic impact of the Younger Dryas, which initially prevented interglacial carbonate production and delayed its maximum until the mid- Holocene. In contrast, forest expansion was progressive, starting as early as ca. 38,000 ago. The proximity of high mountains and the probable moderating lake effect on local climate conditions promoted forest expansion, and contributed to make the surroundings of Lake Ohrid favourable to forest refugia during the last glacial, usually steppic, period. Our study of sedimentology, mineralogy, geochemistry, magnetics, palynology and isotopes illustrates the non-linear response of terrestrial and lacustrine ecosystems to similar climate events, and demonstrates the potential of Lake Ohrid as an excellent paleoclimatic archive during the Quaternary. URI: http://hdl.handle.net/10311/607 Files in this item: 1
LakeOhrid.pdf (1.662Mb) -
Ringrose, S.; Jellema, A.; Huntsman-Mapila, P.; Baker, L.; Brubaker, K. (Taylor & Francis; http://www.tandf.co.uk/journals/titles/01431161.asp, October 10, 2005)[more][less]
Abstract: This work determines the value of remotely sensed imagery in developing drying impacts which occur as a result of internal and/or external factors in the Okavango catchment. Three sites provide a preview of the consequences of Delta margin drying as depicted over historical, intermediate and geological timescales. Initially, supervised classification resulted in the identification of sequences of islands and flood plains and their associated vegetation cover on ETM+ imagery, with a classification accuracy of 74- 77%. Comparative results, augmented by patch analysis, suggest that through time, island woody vegetation cover has invaded the flood plains and locally developed protected ecotonal areas (extensions) which are densely treed, relative to adjacent, non-protected flood plains. Over longer time periods, protected areas between extensions became infilled with woody vegetation leading to, in effect, island enlargement or agglomeration. Disadvantages of long-term Delta drying in terms of natural resource management include a reduced availability of wetland-based construction and agricultural resources. If natural regeneration (island agglomeration) is allowed to take place, these resources may ultimately be replaced by dryland timber and potential cropland. URI: http://hdl.handle.net/10311/174 Files in this item: 2
license.txt (1.998Kb)ringrose_int_j_remote_sensing_2005.pdf (3.625Mb) -
Huntsman-Mapila, P.; Ringrose, S.; Downey, W.S.; Modisi, M.; Coetzee, S.H.; Tiercelin, J-J.; Kampunzu, A.B.; Vanderpost, C. (Elsevier; http://www.elsevier.com/wps/find/journaldescription.cws_home/865/description#description, February 7, 2007)[more][less]
Abstract: [Please note chemical formulae do not display correctly in this abstract]. Sediment samples from a continuous 4.6m profile in the dry bed of Lake Ngami in NW Botswana were analysed for geochemistry and dated using both 14C and TL methods. Certain units in the profile were found to be diatom rich and these, with the geochemical results, were used as indicators of high and low lake levels within the basin. The Lake Ngami sediments contain a high proportion of SiO2 (51-92.5 wt%, avg. 72.4 wt%) and variable levels of Al2O3 (2.04-17.2 wt%, avg. 8.88 wt%). Based on elevated Al2O3 and organic matter (LOIorgc) results, lacustrine conditions occurred at ca. 42 ka until 40 ka and diatom results suggest that relatively deep but brackish conditions prevailed. At 40 ka, the lacustrine sedimentary record was terminated abruptly, possibly by tectonic activity. At ca. 19 ka, shallow, aerobic, turbulent conditions were prevalent, but lake levels were at this time increasing to deeper water conditions up until ca. 17 ka. This period coincides with the Late Glacial Maximum, a period of increased aridity in the central southern Africa region. Generally, increasing Sr/Ca ratios and decreasing LOIorgc and Al2O3, from ca. 16 to 5 ka, suggest decreasing inflow into the basin and declining lake levels. Based on the enrichment of LREE results, slightly alkaline conditions prevailed at ca. 12 ka. Diatom results also support shallow alkaline conditions around this time. These lake conditions were maintained primarily by local rainfall input as the region experienced a warmer, wetter phase between 16 and 11 ka. Lake levels rose rapidly by 4 ka, probably in response to enhanced rainfall in the Angolan catchment. These results indicate that lake levels in the Lake Ngami basin are responding to rainfall changes in the Angolan catchment area and local rainfall. The results confirm that the present-day anti-phase rainfall relationship between southern Africa and regions of equatorial Africa was extant during the late Quaternary over the Angolan highlands and NW Botswana. URI: http://hdl.handle.net/10311/152 Files in this item: 2
huntsman_mapila_quatint.pdf (5.573Mb)license.txt (1.998Kb) -
Ringrose, S.; Matheson, W.; Wolski, P.; Huntsman-Mapila, P. (Elsevier; www.elsevier.com/locate/jaridenv, NaN, 2003)[more][less]
Abstract: Vegetative response aspects of climate change studies include the determination of vegetation cover changes across climatic gradients. Vegetation characteristics and soil moisture measurements were obtained from four locations with decreasing rainfall along the Botswana Kalahari transect. These are referred to as Pandamatenga, (698mmyear_1), Maun (460 mmyear_1), Okwa (407 mmyear_1) and Tshane (365 mmyear_1). Trends in major vegetative cover and soil components included species types and richness assessments which reflected certain changes southward but also showed interesting degrees of variability. This occurred despite the apparent homogeneity of the Kalahari sands and predominantly semi-arid savanna shrubâ woodland vegetation cover. Despite linear decreases, both in rainfall and soil moisture content, results indicated high soil moisture variability at the Okwa location which relates to unique climatic and geological factors. Also many species are unique to specific locations for instance Pandametanga is characterized by Zambesian species while the Maun location is characterized by Colophosphermum mopane. This changes southwards as Acacias become more dominant and significantly co-occur with Grewia flava. While the average total numbers of plants decreased, total numbers of different species varied little from the wetter to the drier end of the moisture gradient. The association between rainfall and woody cover is negative implying that canopy cover extents (in terms of vegetation density) increase along the gradient due to increases in bush encroachment in drier areas. Therefore, while representing a continuum in terms of species numbers, in other respects (e.g. species types and ground cover components) vegetation zones in the Kalahari may be regarded as discontinuous units. Differences between mapped vegetation zones may be accounted for in terms of relatively unique ecosystem factors which function partly in response to geological conditions and partly in response to local (as opposed to regional) climatic factors. This appears to have led to ecosystem adaptive measures (in terms of species responses) rarely mirrored elsewhere along the gradient. Hence adaptability in terms of species migrations in response to relatively rapid climate changes may not readily take place over the Kalahari in Botswana. URI: http://hdl.handle.net/10311/175 Files in this item: 2
license.txt (1.998Kb)ringrose_jae_2003.pdf (3.823Mb)
Now showing items 1-9 of 9