Browsing Faculty of Science by Author "Steel, P G"
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Bwire, R N; Majinda, R R; Masesane, I B; Steel, P G (International Union of Pure and Applied Chemistry. http://stage.iupac.org/publications/pac/, NaN, 2009)[more][less]
Abstract: The Diels–Alder adducts of ethyl (E)-3-nitroacrylate and furan provided a common and versatile template for the stereocontrolled synthesis of an isomer of the natural product oryzoxymycin and polyhydroxylated cyclohexyl β-amino acid derivatives. The strategy for the synthesis of the polyhydroxylated cyclic β-amino acid derivatives involved base-induced fragmentation of the oxanorbornene skeleton and face selective oxidation reactions. A Pd-catalyzed transfer hydrogenation reaction in the presence of organic acids is also described. This reaction is amenable to being enantioselective through use of optical pure chiral organic acids. URI: http://hdl.handle.net/10311/301 Files in this item: 1
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