Browsing Faculty of Science by Author "Nijegorodov, N."
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Nijegorodov, N.; Luhanga, P.V.C.; King, J.G. (Regional Energy Resources Information Center (RERIC) Asian Institute of Technology. http://www.rericjournal.ait.ac.th/index.php/reric/index, December NaN, 2005)[more][less]
Abstract: Please refer to the attached article for the ABSTRACT. Due to technical problems with some scientific formulae it was not possible to upload the abstract HERE. URI: http://hdl.handle.net/10311/408 Files in this item: 1
Nijegorodov_IEJ_2005.pdf (2.539Mb) -
Mabbs, R.; Nijegorodov, N.; Downey, W.S. (Elsevier Science Ltd. www.elsevier.com/locate/saa, NaN, 2003)[more][less]
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Nijegorodov, N.; Winkoun, D.P.; Nkoma, J.S. (Elsevier Science Ltd http:www.elsevier.com/locate/saa, NaN, 2003)[more][less]
Abstract: Please refer to the attached article for an ABSTRACT. The abstract was not uploaded here due to formula appearance problem in UBRISA. URI: http://hdl.handle.net/10311/403 Files in this item: 1
Nijegorodov_SAa60_2004.pdf (1.056Mb) -
Nijegorodov, N.; Winkoun, D.P.; Nkoma, J.S. (Elsevier Science Ltd. www.elsevier.com/locate/saa, NaN, 2004)[more][less]
Abstract: The fluorescence and laser properties of seven specially chosen aromatic compounds are studied at 293 ◦C. The quantum yield of fluorescence, γ, decay times, τf , of the deaerated and non-deaerated solutions are measured. The oscillator strength, fe, fluorescence rate constants, kf , natural lifetimes, τT 0 , and intersystem crossing rate constants, kST, are calculated. Some laser parameters are calculated or measured experimentally. It is found that the position of the T level plays an important role in the fluorescence and laser properties of aromatic compounds. If the T level is situated below the Sp level, it decreases the quantum yield of fluorescence and the decay time and increases the threshold of laser action. If, due to some structural changes of a molecule, the T level is situated higher than the Sp level, then the quantum yield of fluorescence and the decay times are increasing and the threshold of laser action is decreasing. Such influence of the position of the T level upon fluorescence and laser properties of aromatic compound is explained by the fact that the Sp level mixes with the T level more readily than with other τ ∗ levels. URI: http://hdl.handle.net/10311/366 Files in this item: 1
Nijegorodov_SAa60_2004.pdf (1.056Mb) -
Nijegorodov, N.; Mabbs, R.; Winkoun, D.P. (Elsevier Science Ltd. www.elsevier.com/locate/saa, NaN, 2003)[more][less]
Abstract: Please refer to the attached article for an ABSTRACT. The abstract was not uploaded here due to formula appearance problem in UBRISA. URI: http://hdl.handle.net/10311/402 Files in this item: 1
Nijegorodov_SAa59-2003.pdf (1.367Mb) -
Nijegorodov, N.; Mabbs, R. (Elsevier Science BV; www.elsevier.com/locate/saa, January 15, 2002)[more][less]
Abstract: [Please note that the mathematical symbols have not transposed into this abstact].The luminescent and laser properties of heteroaromatic and aromatic compounds are reviewed and discussed on the basis of all possible mutual arrangements of singlet and triplet states. All heteroaromatic compounds are divided into five classes. It is shown that a heteroaromatic compound can only be an effective laser dye if it belongs to class V (a situation where the Tn_* level lies at higher energy than the S__* 1 level). Moreover, it is shown that the energy interval between the Tn_* and S__* 1 states must be no less than 1000 cmâ 1 since the rate constant of the non-radiative process S__*1 _Tn_*_T__1 is usually 100 times greater than the fluorescence rate constant. The classification is extended to compounds with orbitals of _l,_*, _,__* and _l,__* nature. Pure aromatic compounds, the spectral-luminescent properties of which are solely determined by transitions of _-electrons (_ _ _*), are also divided into five classes, depending on the mutual arrangement of the Sp(1La), S_(1Lb), Tp(3La) and T_(3Bb) states. It is found that only aromatic compounds of classes IV and V can be effective scintillators and laser dyes. It is also shown that the energy interval S_â Sp (for class IV) and T_â Sp (for class V) must be no less than 1000 cmâ 1. To illustrate the classifications for heteroaromatic and aromatic compounds, 12 specifically chosen compounds were studied experimentally and quantum chemically. The quantum yields, _ and decay times, _f of fluorescence in aerated and non-deaerated ethanol or cyclohexane solutions were measured. The oscillator strength, fe, fluorescence rate constant, kf, natural lifetimes, _0 T and intersystem crossing rate constants, kST are calculated. The laser ability of each of the compounds studied is tested. The suggested classification schemes can be extremely useful in the quest for effective scintillators and laser dyes among hypothetical heteroaromatic and aromatic molecules, enabling evaluation of these properties for a particular compound using only quantum chemical simulations. URI: http://hdl.handle.net/10311/136 Files in this item: 2
license.txt (1.998Kb)nijegorodov_sa_2002.pdf (1.811Mb) -
Nijegorodov, N.; Zvolinski, V.; Luhanga, P.V.C.; Mabbs, R.; Ahmad, J. (Elsevier Ltd. www.elsevier.com/locate/saa, NaN, 2006)[more][less]
Abstract: The multi-banded fluorescence and laser properties of 11 new amino- and tosylamino derivatives of 2,5-di(phenyl)-1,3,4-oxadiazole and oxadiazole in various solvents at 293 K are reported. All the compounds investigated possess intra-molecular hydrogen quasi-bond (IHB) of 4.6-5.2 kcal mol-1 in the ground state. In the excited state they can undergo protolytic dissociation or intra-molecular photon-initiated transfer of proton and reveal anomalous fluorescence which cannot be explained within the framework of the Kasha and Kasha-Vavilov rules. Depending upon the excitation wavelength, solvent, concentration and pH of the medium, the compounds studied show a single, double, triple or even a four-banded fluorescence, which has not been reported earlier. The nature of multi-banded fluorescence is explained in terms of the possible photochromic processes in excited states. Quantum yields and decay times of the different fluorescence bands are reported. Anomalous dependence of quantum yield upon concentration of the solution is observed. Laser properties of the compounds studied are carefully tested. Laser action based on the fluorescence of the so-called bi-radical molecules is reported. Various possible arrangements of singlet and triplet levels of compounds investigated are discussed. URI: http://hdl.handle.net/10311/176 Files in this item: 2
license.txt (1.998Kb) -
Nijegorodov, N.; Zvolinsky, V.; Luhanga, P.V.C. (Elsevier Science Ltd. www.elsevier.com/locate/jphotochem, NaN, 2008)[more][less]
Abstract: Intramolecular processes and fluorescence properties of 32 specially chosen aromatic molecules, different in degrees of planarity and rigidity, but family related in -structure are experimentally and theoretically (using the PPP-method) studied at room temperature (293 K). The quantum yields of fluorescence , and decay times τf, of deaerated and non-deaerated cyclohexane solutions are measured. The oscillator strength fe, the fluorescence rate constants kf, the natural lifetimes τT o , and the intersystem crossing rate constants kST, are calculated. The investigations showed the following differences in the behaviour of the fluorescence parameters in transition from the non-planar molecule to the planar and more rigid-type: the value of the symmetry line wave-number υ00 (the frequency of the S0→S1 * transition) and the Stokes shift υST, decrease. The oscillator strength and fluorescence constant, normally decrease. The change in the quantum yield of the fluorescence depends upon the changes in the kf and kST values. Furthermore, the intersystem crossing rate constant generally decreases, sometimes very significantly. However, there are some interesting exceptions. For example, the kST value of the non-planar molecule of 9,10-diphenylanthracene is less than the kST value of the planar and very rigid molecule of anthracene. This important phenomenon is explained. The differences of the intramolecular processes of planar and non-planar molecules are discussed. The photochemical stability of planar and non-planar molecules is studied. The effect of planarity, rigidity and molecular symmetry upon laser properties is also traced. URI: http://hdl.handle.net/10311/367 Files in this item: 1
Nijegorodov_JPPaC196_2008.pdf (1.901Mb)
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