Browsing Faculty of Science by Author "Kumar, P."
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Kumar, J.; Kumar, P.; Suri, N.; Ahmad, M.; Thangaraj, R.; Sathiaraj, T.S. ( NaN, 2008)[more][less]
Abstract: Optical properties of Pb doped ternary Ge-Sb-Te chalcognide films prepared by thermal evaporation have been studied in the visible and near-infrared spectral regions. The straightforward analysis proposed by Swanepoel has been successfully employed and it has allowed us to accurately determine the refractive index and extinction coefficient of the films. The refractive index has been determined from the upper and lower envelopes of the transmission spectra. The absorption coefficient and extinction coefficient have been determined from the transmission spectra in the strong-absorption region. The dispersion of the refractive index is discussed in terms of the Wemple–DiDomenico single oscillator model. URI: http://hdl.handle.net/10311/544 Files in this item: 1
Effect of composition.pdf (950.3Kb) -
Kumar, P.; Sathiaraj, T.S.; Thangaraj, R. (Taylor & Francis, NaN, 2010)[more][less]
Abstract: The measurements and analysis of optical transmission and far-infrared (IR) reflectivity spectra of thermally evaporated Sb2Se3:Sn films are reported. The refractive index and film thickness have been determined from the upper and lower envelopes of the transmission spectra (Swanepoel’s standard envelope method), measured at normal incidence, in the spectral range from 800 to 2500 nm. Values of the refractive index fit well to Cauchy’s dispersion relation. The optical gap decreases with an increase in the Sn content, while a maximum in the tailing parameter and Urbach’s energy occurs with only a small amount ( 1 at %) of this additive. Characteristic vibrational bands for SbSe3 structural units are revealed in the far-IR spectrum with no additional ones arising from the Sn additive. The Kramers–Kronig analysis has been used to calculate the dielectric constants and hence the longitudinal optic and transverse optic splitting for various compositions. The inclusion of Sn as a charged entity along with the Coulomb interactions which serve to polarize the glass medium is found to be responsible for these results. URI: http://hdl.handle.net/10311/547 Files in this item: 1
Optical properties.pdf (1.116Mb) -
Kumar, P.; Thangaraj, R.; Sathiaraj, T.S. (Springer Netherlands, NaN, 2008)[more][less]
Abstract: The melt-quenched Sn10Sb20Se70 sample in the bulk form was used to prepare films on well-cleaned glass substrates by thermal evaporation method. The activation energy for glass transition (apparent) and crystallization has been analyzed by using the Kissinger formulation. The X-ray diffraction study shows the crystallization of Sb2Se3 phase in the major proportion as compared to the SnSe2 phase. The SEM images film of the show the appearance of spherical globules upon annealing below the glass transition temperature. The effect of annealing temperature on the electrical and optical properties has been studied. A linear fit between DE and Eo is observed, indicating the validity of Meyer–Neldel rule with the change in the annealing temperature. Description: some mathematical symbols may not come as they are in the title and abstract. URI: http://hdl.handle.net/10311/691 Files in this item: 1
Thermal analysis.pdf (949.2Kb)
Now showing items 1-3 of 3