Browsing Faculty of Science by Author "Atlhopheng, J."
Now showing items 1-5 of 5
-
Meck, M.; Atlhopheng, J.; Masamba, W.R.L. (Elsevier http://www.linkinghub.elsevier.com/retrieve/pii/S1464343X09000491, NaN, 2009)[more][less]
Abstract: Alkaline rocks (phosphate deposits in particular) of igneous origin are currently being mined in Zimbabwe. Exploitation of these deposits, which are associated with metals and non-metals, provides a potential for changing the river water quality in the surrounding areas by increasing metal and phosphates levels in the water, thereby endangering the beneficial use of the river. The aim and objectives of this paper are to enumerate the current impacts associated with mining alkaline rocks on Save River water quality in Zimbabwe using the Dorowa mine as a case study. Though there are several impacts associated with the mining of alkaline rocks, this paper deals only with impacts on water quality. A preliminary assessment of the water quality in the Save River downstream of the Dorowa phosphate mine showed an increase in conductivity, iron content, manganese content, nitrates and hardness when compared to those taken before mining activity began. However, there was no notable increase in phosphate and metals except for Fe and Mn. A plausible explanation for the low phosphate values in the water is that the phosphates are precipitating and settling as sediments. Phosphate is known to effectively remove metals from the surface water through the formation of metal–phosphate minerals. Thus, various pollutants may be adsorbed into sediments accumulated on the bottom of the river. These sediments may accumulate pollutants over long periods and act as new pollutant sources to the overlying water when phosphate desorbs from sediments due to changes in water conditions. Therefore, the sediments can act as a source of water pollution in the future URI: http://hdl.handle.net/10311/409 Files in this item: 1
Meck_JAES_2009.pdf (495.8Kb) -
Meck, M.L.; Atlhopheng, J.; Masamba, W.R.L.; Ringrose, S.; Diskin, S. (Bentham Open, http://www.benthamscience.com/open/tomj/index.htm, NaN, 2011)[more][less]
Abstract: This study set out to establish the major minerals at Dorowa and determine which of those are likely to host metals that may leach into surface and groundwater. This study comes after a preliminary assessment of the water quality in the Save River downstream of the Dorowa phosphate mine in Zimbabwe showed an increase in conductivity, iron content, manganese content, nitrates and hardness when compared to those taken before the mining area. X-Ray Diffractometry (XRD) was used to establish the major minerals at Dorowa whilst Inductively Coupled Plasma Mass Spectrometry (ICP- MS) was used to establish the chemistry of the rocks. The results from this study show that the major minerals in the rocks around Dorowa are feldspars, pyroxenes, apatite, magnetite and calcite. The metals hosted by the rocks include Ag, As, Be, Cd, Co, Cu, Pb, Hg, Ni, Sb, Se and Zn. The study concludes that the minerals likely to host metals are calcite and apatite. Metal hosting is higher in apatite minerals than in calcite. Metal hosting by the other minerals observed in the study area is low. URI: http://hdl.handle.net/10311/1109 Files in this item: 1
Atlhopheng_OMJ_2011.pdf (848.6Kb) -
Meck, M.L.; Masamba, W.R.L.; Atlhopheng, J.; Ringrose, S. (Elsevier Science Ltd, http://www.elsevier.com/locate/pce, NaN, 2011)[more][less]
Abstract: The objective of the study was to investigate the role played by the natural environment in protecting the transboundary Save River from the impacts of metals derived from phosphate mining at Dorowa. The study is a follow up study from a previous one that noted that there is natural attenuation at Dorowa. Water and sediment samples were collected in the Save River and the streams that drain the Dorowa dumps. Inductively coupled plasma mass spectrometry (ICP–MS) was used to analyze the cations (Na+, K+, Ca2+, Mg2+, Cu2+, Co2+, Fe2+, Ni2+, Zn2+, Pb2+, Sn2+, Mn2+, Cd2+) in the samples. Major anions Cl , SO2 4 and NO 3 were analyzed by standard chromatography whilst CO2 3 and HCO 3 were determined by titration. pH was measured on site. Geochemical modeling of the water composition was conducted with Visual Minteq. The results show that natural attenuation is being achieved through precipitation of solids from the water and subsequent deposition onto the sediments. Six of the metals are almost completely precipitated (Cu 99.99%, Fe 99.39%, Ni 91.24%, Pb 99.87%, Sn 99.99% and Zn 88.66%). However Mn, Co and Cd remain in solution. Thus the natural environment is protecting the Save River which is a transboundary river from the impacts of mining through precipitation of the metals. Users downstream of Dorowa mine are therefore not being affected by mining pollution. This study demonstrates that besides being a legitimate and important user of water, the natural environment can also play a significant role in protecting water quality by attenuating metals naturally. By analyzing costs incurred in several places where alternative methods are employed to remediate metal related pollution the study concludes that natural remediation at Dorowa is saving the nation in environmental costs. Therefore the paper advocates for appreciation of the role that the natural environment plays in protecting ecosystems from the impact of human developments and environmental costs. Subsequently, this calls for recognition of natural environment’s role in water resources management for the sustenance of ecosystems and peoples livelihoods. URI: http://hdl.handle.net/10311/963 Files in this item: 1
Atlhopheng_PCE_2011.pdf (630.3Kb) -
Meck, M.L.; Atlhopheng, J.; Masamba, W.R.L.; Ringrose, S. (Elsevier Science Ltd, http://www.elsevier.com/locate/pce, NaN, 2010)[more][less]
Abstract: The study set out to determine the weathering and dissolution of metal hosting minerals at Dorowa for purposes of deducing pollution potential to the nearby Save River. Phosphate rock is mined at Dorowa for the production of phosphate fertilizer. The major minerals found in the ring complex are feldspars, pyroxenes, apatite, magnetite and calcite. Chemical analysis established that the rocks are associated with metals that include copper, lead, zinc, cobalt, nickel, tin and cadmium. Among the many minerals present apatite and calcite host metals more than the other minerals due to their crystal structure. This study investigated the weathering and dissolution of these two minerals. Both apatite and calcite dissolve in natural environmental conditions prevalent at Dorowa. From the analysis the study concludes that the potential availability of metals trapped in the calcite and apatite structures is high. The understanding of weathering and dissolution of metal hosting minerals is important in predicting quality of water around the study area, because most villagers use the Save River as their primary drinking water source. URI: http://hdl.handle.net/10311/1021 Files in this item: 1
Atlhopheng_PCE_2010.pdf (758.1Kb) -
Shaikh, M.; Moleele, N.; Ekosse, G.I.E.; Totolo, O.; Atlhopheng, J. (JASEM http://www.ajol.info/index.php/jasem/article/view/43693/27216, June NaN, 2006)[more][less]
Abstract: Since 1988 Botswana has been experiencing an unprecedented increase in vehicular traffic which is suspected to be having contamination effects on soils along heavily used roads in the country. This study aimed at understanding the contamination trends of heavy metals on soils due to vehicular emissions. The soil physicochemistry (bulk density, particle size distribution, pH, electrical conductivity and cation exchange capacity), mineralogy (using x-ray diffraction techniques) and heavy metals (Cd, Pb, Cu and Zn) concentrations were determined for soil samples obtained along the roadside at 2m, 4m, 6m and 100 m of the Gaborone – Tlokweng Emigration/Immigration Boarder Post Road, which is one of the busiest in the country. Bulk density of soil samples were from 1.19 to 1.4; and sand, loamy sand and sandy loam textural classes constituted the soil samples. The soil pH was from 5.09 to 8.57; the EC ranged from 6.27 μS cm-1to 20.3 27 μS cm-1 and the CEC values were from 10.2 meq100g-1 to 27.2 meq100g-1. Clay minerals were identified in the samples as well as feldspar and quartz. The concentration levels for Pb were from 0 mgkg-1 to 71 mgkg-1; Zn were from 5.23 mgkg-1 to 51.26 mgkg-1 ; Cu were from 0.3 mgkg-1 to 18.1 mgkg-1 and Cd 0 mgkg-1 to 2.4 mgkg-1 . The interplay of soil physico-chemistry and mineralogy on heavy metals concentrations is discussed. Although levels of heavy metals concentrations fell below normal ranges, the values obtained were generally higher than those from some developed and developing countries. URI: http://hdl.handle.net/10311/361 Files in this item: 1
Shaikh_JASEM_2006.pdf (1.018Mb)
Now showing items 1-5 of 5