Browsing Faculty of Science by Title
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Murty, V.R.K.; Karunakara, N. (Elsevier, www.elsevier.com/locate/radmeas, NaN, 2008)[more][less]
Abstract: Studies on concentrations of primordial radionuclides in soil samples of Botswana were carried out. Measurements were made by gamma spectrometry employing a 41% relative efficiency HPGe detector. The activity of 226Ra was found to vary in the range 6.1–97.4 Bq kg 1 with a mean value of 34.8 Bq kg 1, 232Th in 7.4–110.0 Bq kg 1 with a mean value of 41.8 Bq kg 1 and that of 40K between 33.5 and 1085.7 Bq kg 1 with a mean value of 432.7 Bq kg 1 in surface soils. Existence of strong correlations in the distributions of these radionuclides indicates that an individual result for any one of the radionuclide is a good predictor of the concentration of the other. The mean value of effective dose, due to the 238U series, 232Th series and 40K in soil, was 0.07 mSV. The results of the present study are compared with the literature values reported for other normal background regions of the world and discussed. URI: http://hdl.handle.net/10311/493 Files in this item: 1
Murty2008SoilSamples.pdf (782.0Kb) -
Hambira, W.L. (Elsevier, http://www.elsevier.com/wps/find/journaldescription.cws_home/413/description#description, NaN, 2007)[more][less]
Abstract: Natural Resource Accounting (NRA) has become an important environmental/natural resources management tool in recent years. It provides information on stocks of a resource available at a particular point in time and what activities the resource is being used for. The conventional System of National Income Accounts (SNA) normally does not capture the cost of depletion, degradation or pollution of natural resources. This encourages unsustainable use of natural resources since the costs are not reflected when assessing the country’s economic performance or development progress. NRA is thus an attempt to integrate environmental issues into the conventional national accounts. The water sector is one sector that could greatly benefit from this natural resource management tool. Botswana has adopted NRA as a natural resource management tool and has so far developed accounts for minerals, livestock and water. The focus of this paper is on Water Accounting (WA) in relation to Integrated Water Resources Management (IWRM). IWRM is concerned with coordinated development and management of water in order to maximise economic and social welfare without compromising the sustainability of ecosystems. WA helps fill data gaps since it provides the required information for IWRM to be achieved. The aim of this paper therefore is to evaluate the Water Accounts of Botswana Report of 2006 to determine the extent to which it can contribute to integrated water resources management. The paper is based on literature review and the results show that: the available water stocks vary depending on rainfall patterns, well fields are over utilised, there has been growth in consumption, and more than 80% of the waste water produced is not being put to use. These results calls for changes in policies, role of institutions and practices pertaining to water resources management which is what IWRM is all about hence the paper concludes that indeed WA can contribute to the realisation of IWRM. URI: http://hdl.handle.net/10311/283 Files in this item: 1
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Cailteux, J.L.H.; Kampunzu, A.B.; Lerouge, C. (Elsevier www.elsevier.com/locate/gr, NaN, 2007)[more][less]
Abstract: Rocks of the Neoproterozoic Mwashya Subgroup (former Upper Mwashya) form the uppermost sedimentary unit of the Roan Group. Based on new field and drill hole observations, the Mwashya is subdivided into three formations: (1) Kamoya, characterized by dolomitic silty shales/ siltstones/sandstones and containing a regional marker (the “Conglomerate de Mwashya” bed or complex); (2) Kafubu, formed by finely bedded black carbonaceous shales; and (3) Kanzadi, marked by feldspathic sandstones. Rocks of the Mwashya Subgroup are overlain by the Sturtian age Grand Conglomérat diamictite (equivalent to the Varianto/Brazil and Chuos/Namibia diamictites), and conformably overlie rocks of the Kansuki Formation (former Lower Mwashya), a carbonate unit containing volcaniclastic beds. New geochemical data confirm the continental rift context of this magmatism, which is contemporaneous with rift-related volcanism of the Askevold Formation (Nosib Group, Namibia). A gradational lithological transition between rocks of the Kansuki and the underlying Kanwangungu Formations, and similar petrological composition of these two formations, support the hypothesis that the Kansuki is the uppermost unit of the carbonate-dominated Dipeta/Kanwangungu sequence, and does not form part of the Mwashya Subgroup. Base metal deposits, mostly hosted in rocks of the Kansuki Formation, include weakly disseminated early-stage low-grade Cu–Co mineralisation, which was reworked and enriched, or initially deposited, by metamorphic fluids associated with the Lufilian orogenic event. URI: http://hdl.handle.net/10311/399 Files in this item: 1
Kampunzu2007Neoproterozoic Mwashya.pdf (2.801Mb) -
Ntshwene, K.; Kashiwagi, J.; Kashiwagi, D. (Royal Institute of Chartered Surveyors http://www.rics.org/site/download_feed.aspx?fileID=5042&fileExtension=PDF, NaN, 2009)[more][less]
Abstract: The traditional contracting/delivery system in Botswana, introduced by the US, UK, and European educators, consultants, and practitioners, has not been working well in Botswana. The poor project delivery system results have forced the organization of a new group, the Government Implementation Coordination Group (GICO) to attempt to solve the problems. In the fall of 2008, the University of Botswana (UB), through the US State Department sponsored Fulbright program, brought professor Kashiwagi, and the best value Performance Information Procurement System (PIPS) technology, the Information Measurement Theory (IMT), and the Industry Structure Analysis to the UB project management section. This paper proposes that the client’s professional representative requires a new, more effective role. The role includes using performance information, transforming the client’s expectations into a design/construction intent by using expert vendors, ensuring the vendors manage and minimize the risk that they do not control, outsourcing the technical responsibilities, and doing quality assurance instead of quality control. This paradigm will minimize project risk, maximize project value, and increase the professionalism of project management, construction management, and quantity surveyors. These concepts will be tested on three test projects in Botswana. URI: http://hdl.handle.net/10311/473 Files in this item: 1
Ntshwene_COBRA_2009.pdf (1.344Mb) -
Aranibar, J.N.; Otter, L.; Macko, S.A.; Feral, C.J.W.; Epstein, H.E.; Dowty, P.R.; Eckardt, F.; Shugart, H.H.; Swap, R.J. (Blackwell Publishing, January 1, 2004)[more][less]
Abstract: Nitrogen (N) cycling was analyzed in the Kalahari region of southern Africa, where a strong precipitation gradient (from 978 to 230mm mean annual precipitation) is the main variable affecting vegetation. The region is underlain by a homogeneous soil substrate, the Kalahari sands, and provides the opportunity to analyze climate effects on nutrient cycling. Soil and plant N pools, 15N natural abundance (d15N), and soil NO emissions were measured to indicate patterns of N cycling along a precipitation gradient. The importance of biogenic N2 fixation associated with vascular plants was estimated with foliar d15N and the basal area of leguminous plants. Soil and plant N was more 15N enriched in arid than in humid areas, and the relation was steeper in samples collected during wet than during dry years. This indicates a strong effect of annual precipitation variability on N cycling. Soil organic carbon and C/N decreased with aridity, and soil N was influenced by plant functional types. Biogenic N2 fixation associated with vascular plants was more important in humid areas. Nitrogen fixation associated with trees and shrubs was almost absent in arid areas, even though Mimosoideae species dominate. Soil NO emissions increased with temperature and moisture and were therefore estimated to be lower in drier areas. The isotopic pattern observed in the Kalahari (15N enrichment with aridity) agrees with the lower soil organic matter, soil C/N, and N2 fixation found in arid areas. However, the estimated NO emissions would cause an opposite pattern in d15N, suggesting that other processes, such as internal recycling and ammonia volatilization, may also affect isotopic signatures. This study indicates that spatial, and mainly temporal, variability of precipitation play a key role on N cycling and isotopic signatures in the soil–plant system. URI: http://hdl.handle.net/10311/577 Files in this item: 1
ARANIBAR2004NITROGEN CYCLING.pdf (2.135Mb) -
Abegaz, B.M.; Ngadjui, B.T.; Bezabih, M.; Mdee, L.K. (International Union of Pure and Applied Chemistry. http://www.iupac.org/publications/pac/, NaN, 1999)[more][less]
Abstract: Marketed plants are an important but a vulnerable group of plants whose investigations as well as conservation should be considered with priority. The chemistry, and in some cases biological activities of novel iso¯avonoids, nor-lignans, anthracene and naphthalene derivatives and poly prenylated ¯avonoids isolated and characterized from Hagenia abyssinica, Salsola somalensis, Hypoxis spp., Taverniera abyssinica, Aloe spp., Bulbine capitata, Rhamnus prinoides and Dorstenia spp. are discussed. URI: http://hdl.handle.net/10311/289 Files in this item: 1
Novel natural products.pdf (4.533Mb) -
Kaelo, P.; Ali, M.M. (Elsevier; www.elsevier.com/locate/ejor, NaN, 2006)[more][less]
Abstract: Modifications in mutation and localization in acceptance rule are suggested to the differential evolution algorithm for global optimization. Numerical experiments indicate that the resulting algorithms are considerably better than the original differential evolution algorithm. Therefore, they offer a reasonable alternative to many currently available stochastic algorithms, especially for problems requiring 'direct search type' methods. Numerical study is carried out using a set of 50 test problems many of which are inspired by practical applications. URI: http://hdl.handle.net/10311/64 Files in this item: 2
kaelo_EJOP_2006.pdf (1.708Mb)license.txt (1.998Kb) -
Le Gall, B.; Tshoso, G.; Dyment, J.; Kampunzu, A.B.; Jourdan, F.; Fe´raud, G.; Bertrand, H.; Aubourg, C.; Ve´tel, W. (Elsevier www.elsevier.com/locate/jsg, NaN, 2005)[more][less]
Abstract: The structural organization of a giant mafic dyke swarm, the Okavango complex, in the northern Karoo Large Igneous Province (LIP) of NE Botswana is detailed. This N1108E-oriented dyke swarm extends for 1500 km with a maximum width of 100 km through Archaean basement terranes and Permo-Jurassic sedimentary sequences. The cornerstone of the study is the quantitative analysis of NO170 (exposed) and NO420 (detected by ground magnetics) dykes evidenced on a ca. 80-km-long section lying in crystalline host-rocks, at high-angle to the densest zone of the swarm (Shashe area). Individual dykes are generally sub-vertical and parallel to the entire swarm. Statistical analysis of width data indicates anomalous dyke frequency (few data !5.0 m) and mean dyke thickness (high value of 17 m) with respect to values classically obtained from other giant swarms. Variations of mean dyke thicknesses from 17 (N1108E swarm) to 27 m (adjoining and coeval N708E giant swarm) are assigned to the conditions hosting fracture networks dilated as either shear or pure extensional structures, respectively, in response to an inferred NNW–SSE extension. Both fracture patterns are regarded as inherited brittle basement fabrics associated with a previous (Proterozoic) dyking event. The Okavango N1108E dyke swarm is thus a polyphase intrusive system in which total dilation caused by Karoo dykes (estimated frequency of 87%) is 12.2% (6315 m of cumulative dyke width) throughout the 52-km-long projected Shashe section. Assuming that Karoo mafic dyke swarms in NE Botswana follow inherited Proterozoic fractures, as similarly applied for most of the nearly synchronous giant dyke complexes converging towards the Nuanetsi area, leads us to consider that the resulting triple junction-like dyke/fracture pattern is not a definitive proof for a deep mantle plume in the Karoo LIP. URI: http://hdl.handle.net/10311/400 Files in this item: 1
Kampunzu2005Okavangogiant.pdf (3.456Mb) -
Mapeo, R.B.M.; Ramokate, L.V.; Corfu, F.; Davis, D.W.; Kampunzu, A.B. (Elsevier Ltd. www.elsevier.com/locate/jafrearsci, NaN, 2006)[more][less]
Abstract: The Okwa Basement Complex crops out at the northwestern edge of the Kaapvaal craton within the Okwa Inlier, an isolated exposure of Precambrian basement in the Kalahari Desert. New U–Pb zircon dating was performed on all the major Palaeoproterozoic lithologies of the complex. Results are 2055.3 ± 1.3 Ma for augen gneiss, 2056.3 ± 1.3 Ma for foliated monzogranite and 2057 ± 2 Ma for microgranite. A meta-rhyolite gives an age of 2055 ± 4 Ma, based on one concordant zircon, and contains an inherited zircon with an age of 2101 ± 4 Ma. All precisely dated rocks are indistinguishable in age at 2056 ± 2 Ma. This age can be broadly correlated with Palaeoproterozoic geologic events in the Magondi belt at the northwest margin of the Zimbabwe craton and the Triangle Shear Zone in the Limpopo belt. However, the most precise correlation is with the Bushveld Complex, whose age is indistinguishable from that of the Okwa Basement Complex. This suggests a link between marginal and intra-cratonic Bushveld-age magmatism on the Kaapvaal craton. URI: http://hdl.handle.net/10311/272 Files in this item: 1
The Okwa basement complex.pdf (5.655Mb) -
Massamba, F. (Birkhäuser Basel. http://www.springerlink.com/content/107580/?p=1930c3cc1de944feae211b785b3b42a4&pi=0, NaN, 2009)[more][less]
Abstract: We study semi-parallel lightlike hypersurfaces of an indefinite Kenmotsu manifold, tangent to the structure vector field. Some Theorems on parallel and semi-parallel vector field, geodesibility of lightlike hypersurfaces are obtained. The geometrical configuration of such lightlike hypersurfaces is established. We prove that, in totally contact umbilical lightlike hypersurfaces of an indefinite Kenmotsu manifold which has constant φ-holomorphic sectional curvature c, tangent to the structure vector field and such that its distribution is parallel, the parallelism and semi-parallelism notions are equivalent. URI: http://hdl.handle.net/10311/539 Files in this item: 1
On semi-parallel.pdf (1.027Mb) -
Kumar, P.; Sathiaraj, T.S.; Thangaraj, R. (Taylor & Francis, NaN, 2010)[more][less]
Abstract: The measurements and analysis of optical transmission and far-infrared (IR) reflectivity spectra of thermally evaporated Sb2Se3:Sn films are reported. The refractive index and film thickness have been determined from the upper and lower envelopes of the transmission spectra (Swanepoel’s standard envelope method), measured at normal incidence, in the spectral range from 800 to 2500 nm. Values of the refractive index fit well to Cauchy’s dispersion relation. The optical gap decreases with an increase in the Sn content, while a maximum in the tailing parameter and Urbach’s energy occurs with only a small amount ( 1 at %) of this additive. Characteristic vibrational bands for SbSe3 structural units are revealed in the far-IR spectrum with no additional ones arising from the Sn additive. The Kramers–Kronig analysis has been used to calculate the dielectric constants and hence the longitudinal optic and transverse optic splitting for various compositions. The inclusion of Sn as a charged entity along with the Coulomb interactions which serve to polarize the glass medium is found to be responsible for these results. URI: http://hdl.handle.net/10311/547 Files in this item: 1
Optical properties.pdf (1.116Mb) -
Moyo, S.; Gashe, B.A.; Collison, E.K.; Mpuchane, S. (Elsevier / www.elsevier.com/locate/ijfoodmicro, NaN, 2003)[more][less]
Abstract: This present study was undertaken to find optimum conditions of pH, temperature and, period of incubation for the pectinolytic activity of Kluyveromyces wickerhamii isolated from rotting fruits and to assess the effect of these factors by use of response surface methodology (RSM). A central composite rotatable design was used as an experimental design for the analysis of the allocation of treatment combinations. A second order polynomial regression model was fitted and was found adequate, with an R2 of 0.94469 ( P < 0.001). The effects of temperature and pH were the most significant factors in influencing enzyme production. Estimated optimum conditions were as follows: pH 5.0, temperature, 32 jC and an incubation period of 91 h. Pectinesterase (PE), pectin lyase (PL), and cellulase activities were not detected. Pectinase production was partially constitutive. Pectin was degraded by the isolated strain of K. wickerhamii in the current study, and the pectinolytic activity is referred to as polygalacturonase (PG) activity. Crude enzyme extract was thermostable at various temperatures and, stimulated by the presence of Ca2 + ions but inhibited by other ions like Mg2 +, Zn2 +, Co2 +, Mn2 + and Na+. URI: http://hdl.handle.net/10311/228 Files in this item: 2
license.txt (1.998Kb)Moyo_IJFM_2003.pdf (2.012Mb) -
Ringrose, S.; Kampunzu, A.B.; Vink, B.W.; Matheson, W.; Downey, W.S. (John Wiley & Sons, Ltd. http://www3.interscience.wiley.com/journal/117935722/grouphome/home.html, NaN, 2002)[more][less]
Abstract: Quaternary sedimentation in the Moshaweng dry valley of southeastern Botswana is evaluated on the basis of geomorphological evolution and sedimentological analyses. Stratigraphic evidence reveals an 'upper surface (1095 m) containing abundant sil-calcrete, an intermediate surface (1085 m) in which sil-calcrete underlies nodular calcrete and lower (1075 m) surface in which sil-calcrete and nodular calcrete are interbedded. This subdivision is reflected in the geochemical composition of the sediments which show an overall trend of decreasing Si02 content (and increasing CaC03 content) with depth from the highest to the lowest surface levels. The calcretes and sil-calcretes represent modifications of pre-existing detrital Kalahari Group sand and basal Kalahari pebbles which thinned over a Karoo bedrock high. Modification took place during wet periods when abundant Ca++ -rich groundwater flowed along the structurally aligned valley system. With the onset of drier conditions, water table fluctuations led to the precipitation of nodular calcretes in the phreatic layer to a depth of about 20 m. A major geochemical change resulted in the preferential silicification of the nodular calcrete deposits. Conditions for silica mobilization may be related to drying-induced salinity and in situ geochemical differentiation brought about by pebble dissociation towards the top of the sediment pile. As calcretization and valley formation progressed to lower levels, silica release took place on a diminishing scale. Thermoluminescence dating infers a mid-Pleistocene age for sil-calcrete formation suggesting that valley evolution and original calcrete precipitation are much older. Late st~ge dissolution of CaC03 from pre-existing surface calcretes or sil-calcretes led to the formation of pedogenic case-hardened deposits during a time of reduced flow through the Moshaweng system possibly during the upper or late Pleistocene. URI: http://hdl.handle.net/10311/310 Files in this item: 1
Ringrose_ESPL_2002.pdf (3.095Mb) -
Ringrose, S.; Harris, C.; Huntsman-Mapila, P.; Vink, B.W.; Diskins, S.; Vanderpost, C.; Matheson, W. (Elsevier www.elsevier.com/locate/sedgeo, NaN, 2009)[more][less]
Abstract: Trace elements togetherwith some O and C isotope analysiswere undertaken on duricrust strandline deposits in the palaeo-Makgadikgadi sub-basin (PMSB) to provide insight into palaeo-climatic conditions through the interpretation of calcrete, silcrete–calcrete intergrade and silcrete deposits. Trace element content and relative abundance suggest that the duricrust origins are associated with the long-term weathering of the Karoo Large Igneous Province which underlies the PMSB. This work shows that duricrust origins are related to Ca2+ and Si (and associated trace elements) being transported mainly through the groundwater and then subsequently precipitated at different strandline elevations over time. Local groundwater feeding in towards the pan margin and accumulating in near-neutral pan-marginal pools, appears to facilitate Si concentration and permeation of pre-existing calcretes. The silica precipitates as the pH drops when renewed freshwater enters the pools. Hence the inferred palaeo-climatic regime for silcretisationmay be similar to that occurring in Botswana at present being dry semi-arid with lowseasonal rainfall. In contrast the extensive calcrete precipitation in the strandlines results from abundant Ca2+ in adjacent waters which appear to be derived from both local and regional sources. The arrival of Ca2+ from regional sources (shown by trace element evidence) infers heavy rainfall in the upper catchment suggesting a major humid event followed by regional drying. Palaeo-climatic inferences suggest the juxtaposition ofmajor humid events interspersedwithmore normal semi-arid palaeo-climateswith an exception obtained from isotope data, of drier and cooler conditions than usual for the region around 80–90000 years ago. Whereas trace element data can greatly assist in the interpretation of complex deposits such as duricrusts, care should be taken over the use of particular ratios (such as Yb/Gd ratio) which may produce spurious results. URI: http://hdl.handle.net/10311/560 Files in this item: 1
RINGROSE2009Makgadikgadi Pans.pdf (3.500Mb) -
Milesi, J.P.; Toteu, S.F.; Deschamps, Y.; Feybesse, J.L.; Lerouge, C.; Cocherie, A.; Penaye, J.; Tchameni, R.; Moloto-A-Kenguemba, G.; Kampunzu, H.A.B.; Nicol, N.; Duguey, E.; Leistel, J.M.; Saint-Martin, M.; Ralay, F.; Heinry, C.; Bouchot, V.; Mbaigane, J.C. Doumnang; Kula, V. Kanda; Chene, F.; Monthel, J.; Boutin, P.; Cailteux, J. (Elsevier www.elsevier.com/locate/jafrearsci, NaN, 2006)[more][less]
Abstract: This paper is prepared within the frameworks of IGCP Project 470 and the associated BRGM scientific project ‘‘Africa 1999–2004’’ to accompany the 1:4,000,000 scale map ‘‘Geology and major ore deposits of Central Africa, presented at the 20th Colloquium of African Geology in Orleans in June 2004. It incorporates geological and metallogenic data from eight countries in Central Africa (Angola, Cameroon, Chad, Central African Republic, Congo Brazzaville, Democratic Republic of Congo (DRC), Equatorial Guinea and Zambia). The map is a harmonised and geo-referenced preliminary map, based on a GIS at 1:2,000,000 scale, and focusses on the spatial and temporal distribution of selected major deposits. URI: http://hdl.handle.net/10311/384 Files in this item: 1
Kampunzu2006MajorOreDeposits.pdf (2.307Mb) -
Batumike, M.J.; Kampunzu, A.B.; Cailteux, J.H. (Elsevier www.elsevier.com/locate/jafrearsci, NaN, 2006)[more][less]
Abstract: The Nguba and Kundelungu Groups constitute the middle and upper parts of the Neoproterozoic Katangan Supergroup, respectively, and consist of conglomerates, sandstones, mudrocks and carbonates. During deposition, the Katangan basin received sediments originating from both northern and southern sources. The Nguba and Kundelungu Groups siliciclastic rocks have elemental abundances and ratios suggestive of a relatively felsic TTG source, although slightly more mafic compositions occur in the Nguba Group and the overlying ‘‘Petit Conglome´rat’’ Formation at the base of the Kundelungu Group. Modal compositions of the Nguba Group rocks indicate a basement uplift provenance, and geochemical parameters indicate the source of both the Nguba and Kundelungu Groups had an active continental margin character. Source area weathering was moderate in the Nguba Group. Low Chemical Index of Alteration (CIA) and Plagioclase Index of Alteration (PIA) indices and relatively uniform chemical compositions of the ‘‘Grand Conglome´rat’’ and the ‘‘Petit Conglome´rat’’ Formations lying respectively at the bases of the Nguba and Kundelungu Groups are compatible with deposition in a cool or frigid climate, and support their presumed petrographic based glaciogenic origin. High CIA and PIA indices in Upper Kalule rocks in the middle part of the Kundelungu Group point to the intensification of source weathering, possibly under tropical to subtropical climate under steady state conditions. Geochemical similarities between the Nguba Group and the ‘‘Petit Conglome´rat’’ are compatible with a change from an extensional setting to compression, with derivation of the ‘‘Petit Conglome´rat’’ by reworking of the underlying units during basin inversion. Change in provenance signatures and weathering indices in the Upper Kalule Formation may reflect reduced tectonism and resumption of supply of more weathered extrabasinal detritus, similar to that which fed the basal Roan Group. Overall the data suggest derivation mainly from pre-Katangan Proterozoic sources with continental arc characteristics. The adjacent Paleoproterozoic Ubendian Belt, particularly the Bangweulu block calcalkaline plutonic and volcanic province, is a suitable candidate as the source for the Nguba and Kundelungu Group sedimentary rocks. However, Mesoproterozoic and Archaean terrains have also contributed a minor component to the basin. URI: http://hdl.handle.net/10311/392 Files in this item: 1
Kampunzu2006Petrologyandgeochemistry.pdf (1.585Mb) -
Kumar, J.; Ahmad, M.; Chander, R.; Thangaraj, R.; Sathiaraj, T.S. (EDP Sciences, NaN, 2008)[more][less]
Abstract: Effect of Pb substitution on the amorphous-crystalline transformation temperature, optical band gap and crystalline structure of Ge2Sb2Te5 has been studied. In Pb:GeSbTe chalcogenide films prepared by thermal evaporation, an amorphous to crystallization transition is observed at 124, 129, 136 and 138 ◦C in Pb0Ge20Sb24Te56, Pb1.6Ge19Sb26Te54, Pb3Ge17Sb28Te53 and Pb5Ge12Sb28Te55 respectively. XRD investigations of annealed samples reveal that Pb substitution retains NaCl type crystalline structure of GST but expands the lattice due to large atomic radii. The increase in amorphous-crystalline transformation temperature is followed with the increase in phase segregation. The optical gap shows marginal variations with composition. URI: http://hdl.handle.net/10311/531 Files in this item: 1
Phase segregation.pdf (573.5Kb) -
Kumar, J.; Ahmad, M.; Chander, R.; Thangaraj, R.; Sathiaraj, T.S. (EDP Sciences. http://www.epjap.org/, NaN, 2008)[more][less]
Abstract: Effect of Pb substitution on the amorphous-crystalline transformation temperature, optical band gap and crystalline structure of Ge2Sb2Te5 has been studied. In Pb:GeSbTe chalcogenide films prepared by thermal evaporation, an amorphous to crystallization transition is observed at 124, 129, 136 and 138 ◦C in Pb0Ge20Sb24Te56, Pb1.6Ge19Sb26Te54, Pb3Ge17Sb28Te53 and Pb5Ge12Sb28Te55 respectively. XRD investigations of annealed samples reveal that Pb substitution retains NaCl type crystalline structure of GST but expands the lattice due to large atomic radii. The increase in amorphous-crystalline transformation temperature is followed with the increase in phase segregation. The optical gap shows marginal variations with composition. URI: http://hdl.handle.net/10311/278 Files in this item: 1
Kumar_EPJAP41_2008.pdf (796.1Kb) -
Goodwin, J.W.; Hughes, R.W.; Kwaambwa, H.M.; Reynolds, P.A. (Elseview Science B.V. www.elsevier.nl/locate/colsurfa, NaN, 2000)[more][less]
Abstract: A series of well characterised cis-polyisoprene polymers have been added to dispersions of PHS coated PMMA particles in dodecane. At a molecular weight of 8000 g mol−1 and above, these systems showed phase separation at low particle volume fractions and above a critical polymer concentration. The rate of separation has been shown to be influenced by the viscosity of the polymer. At high polymer and particle volume fractions long lived metastable phases occurred. Above a critical concentration these were viscoelastic indicating an appreciable change in diffusion dynamics with two relaxation processes present. A significant Bingham yield stress was also observed. The Asakura Oosawa potential was not able to describe the observed rheological properties. At a molecular weight of 1000 g mol−1 no phase separation was observed. At high particle concentrations the yield stress was found to reduce with the addition of polymer. This was due to the polymer acting as a ‘solvent’ and penetrating the stabilising layer on the particles. URI: http://hdl.handle.net/10311/329 Files in this item: 1
Phase separation behaviour.pdf (2.723Mb) -
Munkombwe N.M. (Elsevier Ltd. www.elsevier.com/locate/phytochem, NaN, 2003)[more][less]
Abstract: Two phenylpropanoid glucosides, 2-O-b-d-glucosyloxy-4-methoxybenzenepropanoic acid and its methyl ester, together with syringin and adicardin were isolated from the stem of Gnidia polycephala and characterized by physical and spectroscopic data. URI: http://hdl.handle.net/10311/275 Files in this item: 2
Phenylpropanoid glycosides.pdf (2.288Mb)Phenylpropanoid glycosides of Gnidia.pdf (155.6Kb)